This letter reports a normally-OFF Al2O3/GaN gate-recessed MOSFET using a low-damage digital recess technique featuring multiple cycles of plasma oxidation and wet oxide removal process. The wet etching process eliminates the damage induced by plasma bombardment induced in conventional inductively coupled plasma dry etching process so that good surface morphology and high interface quality could be achieved. The fully recessed Al2O3/GaN MOSFET delivers true enhancement-mode operation with a threshold voltage of +1.7 V. The maximum output current density is 528 mA/mm at a positive gate bias of 8 V. A peak field-effect mobility of 251 cm(2)/V.s is obtained, indicating high-quality Al2O3/GaN interface.

A self-terminating gate recess etching technique is first proposed to fabricate normally off AlGaN/GaN MOSFET. The gate recess process includes a thermal oxidation of the AlGaN barrier layer for 40 min at 615 degrees C followed by 45-min etching in potassium hydroxide solution at 70 degrees C, which is found to be self-terminated at the AlGaN/GaN interface with negligible effect on the underlying GaN layer, manifesting itself easy to control, highly repeatable, and promising for industrialization. The fabricated device based on this technique with atomic layer deposition Al2O3 as gate insulator exhibits a threshold voltage as high as 3.2 V with a maximum drain current over 200 mA/mm and a 60% increased breakdown voltage than that of the conventional high electron mobility transistors.

AlGaN/GaN metal oxide semiconductor high electron mobility transistors (MOSHEMTs) with thick (>35 nm), high-kappa (TiO2/NiO), submicrometer-footprint (0.4 mu m) gate dielectric are found to exhibit two orders of magnitude in lower gate leakage current (similar to 1 nA/mm up to +3-V applied gate bias), higher I-MAX (709 mA/mm), and higher drain breakdown voltage, compared to Schottky barrier (SB) HEMTs of the same geometry. The maximum extrinsic transconductance of both the MOSHEMTs and the SBHEMTs with 2 x 80-mu m gate fingers is measured to be 149 mS/mm. The addition of the submicrometer-footprint gate oxide layer only results in a small reduction of the current gain cutoff frequency (21 versus 25 GHz, derived from S-parameter test data) because of the high permittivity (kappa approximate to 100) of the gate dielectric. This high-performance submicrometer-footprint MOSHEMT is highly promising for microwave power amplifier applications in communication and radar systems.

Kink effects are studied in conventional AlGaN/GaN high-electron-mobility transistors by measuring their current-voltage characteristics with various bias sweeping conditions at drain and gate terminals. It is found that the kink effect is induced by drain and gate pumping. The magnitude of kink is directly related to the maximum drain voltage and current levels during on-state operation. The hot electrons in the 2-D electron gas channel generated under high drain bias could be injected into the adjacent epitaxial buffer layer where they can be captured by donor-like traps. Hot electron trapping and the subsequent field-assisted de-trapping is suggested to be the dominant mechanism of kink generation in the studied device. The extracted activation energy of the traps accounting for the kink effect is 589 +/- 67 meV from temperature-dependent transient measurement, and is close to the energy of the E-2 trap widely reported in GaN layers.

Improvement of the AlGaN/GaN high-electron mobility transistor's (HEMT's) OFF-state breakdown voltage is achieved by implanting (19)F(+) ions at an energy of 50 keV and dose of 1 x 10(12) cm(-2) under the gate region using BF(3) as the source. The charge state of the implanted fluorine ions changes from positive to negative in the AlGaN/GaN structure because of fluorine's strong electronegativity. The negative-charged fluorine ions at the back side of the two-dimensional electron gas can raise the energy barrier of the GaN buffer layer under the channel, effectively blocking the current injected from the source to the high-field region of the GaN channel when the HEMT is biased at OFF-state. The source-injected electrons, if not blocked, could flow to the high-field region and initiate a premature three-terminal OFF-state breakdown in a conventional AlGaN/GaN HEMT. A 38% improvement of the three-terminal OFF-state breakdown voltage and 40% improvement of the power figure-of-merit V(BD-off)(2)/R(on) are achieved in the enhanced back barrier HEMT.

This paper presents a fabrication technology of enhancement-mode AlGaN/GaN high electron mobility transistors (HEMTs) using standard fluorine ion implantation. An 80 nm silicon nitride layer was deposited on the AlGaN as an energy-absorbing layer that slows down the high energy (similar to 25 keV) fluorine ions so that majority of the fluorine ions are incorporated in the AlGaN barrier. The threshold voltage was successfully shifted from -1.9 to +1.8 V, converting depletion mode HEMTs to enhancement-mode ones. The fluorine ion distribution profile was confirmed by Secondary Ion Mass Spectrometry (SIMS). (C) 2011 The Electrochemical Society. [DOI: 10.1149/1.3562273] All rights reserved.

AlGaN/GaN high-electron mobility transistor's (HEMT's) off-state breakdown is investigated using drain-current injection techniques with different injection current levels. Competitions between the source leakage and gate leakage, pure leakage and impact ionization, and source-and gate-injection-induced impact ionization during the drain-injection measurement are discussed in detail. It was found that the breakdown originates from the source/gate leakage at low drain injection levels but is dominated by source/gate-induced impact ionization process at high drain injection currents. The source-induced impact ionization usually precedes the gate-induced impact ionization in low-gate leakage devices, resulting in a premature three-terminal off-state breakdown. We also found that the gate-bias value affects the breakdown voltage in the conventional three-terminal off-state breakdown I-V measurement and should be carefully considered.

Modulations of energy band and polarization field by fluorine ions in fluorine plasma treated AlGaN/GaN heterostructures were revealed by positron annihilation spectroscopy (PAS). It is found that the annihilation probability is mainly governed by the electric field in the AlGaN/GaN heterostructure, which could be modulated by charged ions, opposite to what was first expected from the large number of plasma-induced defects such as Ga-vacancies. The modulation of electric field is successfully observed through the opposite changes in the S parameters on the two sides of the hetero-interface after fluorine plasma treatment due to the opposite E-field directions. Fluorine is experimentally proved to be negatively charged in GaN related materials, which is consistent with the operation principle of enhancement-mode AlGaN/GaN HEMT fabricated by fluorine plasma treatment. It is also suggested that PAS is a useful tool to probe the intrinsic electric field in AlGaN/GaN system. (C) 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim