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Activation of peroxydisulfate by V-Fe concentrate ore for enhanced degradation of carbamazepine: Surface ≡V(III) and ≡V(IV) as electron donors promoted the regeneration of ≡Fe(II)

Citation:

Lai L, Ji H, Zhang H, Liu R, Zhou C, Liu W, Ao Z, Li N, Liu C, Yao G, et al. Activation of peroxydisulfate by V-Fe concentrate ore for enhanced degradation of carbamazepine: Surface ≡V(III) and ≡V(IV) as electron donors promoted the regeneration of ≡Fe(II). Applied Catalysis B: Environmental [Internet]. 2021;282:119559.

摘要:

V-Fe concentrate ore was applied to activate peroxydisulfate (PDS) for carbamazepine (CBZ) degradation. The excellent performance of V-Fe concentrate ore was mainly ascribed to the quick electron transfer from surface ≡V(III) and ≡V (IV) to ≡Fe(III) for ≡Fe(II) regeneration, which was confirmed by XPS and XAS analyses. This accelerated ≡Fe(II) regeneration could thus lead to quick formation of HO, SO4−, O2− and effective degradation of CBZ. The degradation rate of CBZ could be also expressed by a kinetic model, i.e., −d[CBZ]/dt = (0.83 mM-0.55 min-1(g/L)-0.65) [CBZ]0.29[PDS]1.26[V-Fe]0.65. Combined with the measured intermediates and the results of DFT calculation, CBZ degradation pathway was proposed systematically. Moreover, this catalyst displayed excellent recyclability and general applicability for a broad substrate scope. This study suggests low valent vanadium makes crucial contributions to the high activity of V-Fe-based catalysts, and improves the understanding of electron transfer mechanism between V and Fe in PDS activation process.

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