The discovery of superconductivity in layered MgB2 has renewed interest in the search for high-temperature conventional superconductors, leading to the synthesis of numerous hydrogen-dominated materials with high critical temperatures (Tc) under high pressures. However, achieving a high-Tc superconductor under ambient pressure remains a challenging goal. In this study, we propose a novel approach to realize a high-temperature superconductor under ambient pressure by introducing a hexagonal H monolayer into the hexagonal close-packed magnesium lattice, resulting in a new and stable few-hydrogen metal-bonded layered magnesium hydride (Mg4)2H1. This compound exhibits superior ductility compared to multi-hydrogen, cuprate, and iron-based superconductors due to its metallic bonding. Our unconventional strategy diverges from the conventional design principles used in hydrogen-dominated covalent high-temperature superconductors. Using anisotropic Migdal–Eliashberg equations, we demonstrate that the stable (Mg4)2H1 compound is a typical phonon-mediated superconductor, characterized by strong electron–phonon coupling and an excellent Tc of 37 K under ambient conditions, comparable to that of MgB2. Our findings not only present a new pathway for exploring high-temperature superconductors but also provide valuable insights for future experimental synthesis endeavors.
Environmental theoretical calculation aims to use computer simulation to assist in solving environmental problems. Herein, we present the guiding principles of environmental theoretical calculation for non-periodic systems. A summary is given of recent progress towards the use of environmental theoretical calculation to reveal the degradation/transformation mechanisms of contaminants in reactions.
In literary sources we find Amastris a thriving second-century civitas with a much frequented port and an intellectual community (cf. Plin. Ep. 10.98; Luc. Alex. 26ff; Luc. Tox. 57ff), but what of the land that supported it? The Amastriane, as Strabo calls it (Ἀμαστρίανη", Strab. 12.3.10), had a lot of good boxwood, but beyond this much is unclear. This paper takes an epigraphic perspective to discuss observable dynamics in the Amastriane, in two steps.The first step attempts to visualize Christian Marek's hypothetical Amastrian territorium – an administratively defined Amastriane – with Google Earth Pro, using epigraphic findspot information and geographical features Marek identified for the representation. GPS coordinates of field surveys collated by Peri Johnson are added to identify potential settlement locations active in the first to third centuries CE within Marek's proposed territorium. Through the cross-referencing attempt one can observe a cluster of twelve "Amastrian" inscriptions and two settlement mounds (Ören Höyük & Çengelli) in the Eflani Plateau south of the Küre Mountains. This correlation between two sets of data seems to have gone previously unnoticed in relevant scholarship. This paper assumes that inquiry into this cluster of inscriptions and settlement mounds may lead to further insights on the dynamics of an extensive and rugged territory under the control of a civitas during the Principate.The second step interrogates this group of evidence: what can we learn from the assemblage regarding communal diversity, social relations, institutional participation, and connectivity on the periphery of the Amastriane? Of importance is an inscription that specifically refers to an Amastrian archon who was also a genearch of what appears to be a local clan, found at Meyre (approx. 70 km southeast of Amastris; Marek Kat. Amastris no. 95). Scholars have focused more on the cult that the genearch's family worshipped and naos they built, and less if any on the genos' involvement with Amastrian civic institutions. The second key inscription is for a nomikos Demetrios son of Kyrenios (Marek Kat. Amastris no. 97). He was perhaps related to a Chrestes son of Kyrenios and a self-designated Amastrian of the tribe Halicarnassus, who set up a funerary monument at Deresameail (Marek Kat. Hadrianopolis no. 29; 10 km northeast of Hadrianopolis) for his brother-in-law Sextus Vibius Epaphroditus, perhaps related to the Trajanic primipilarius Sextus Vibius Gallus from Amastrian Kytoros. While Corsten and Ruscu have suggested and commented on these relationships, there remains considerable potential to discuss how such relationships formed despite geography, territorial boundaries, institutional divisions, and other inhibiting factors.This paper wishes to suggest that Marek' expansive Amastrian territorium would have initially been a highly fragmented social and political space, but familial recruitment, manumission, intermarriage, and mobility between significant urban centers gradually created common ground for integration. Also, the clan at Meyre may have benefited from intensifying interaction between Amastris, Hadrianopolis and Pompeiopolis, leading to its increased importance and greater participation in Amastrian institutions and norms.
Seismic recordings made during the InSight mission 1 suggested that Mars's liquid core would need to be approximately 27% lighter than pure liquid iron 2,3 , implying a considerable complement of light elements. Core compositions based on seismic and bulk geophysical constraints, however, require larger quantities of the volatile elements hydrogen, carbon and sulfur than those that were cosmochemically available in the likely building blocks of Mars 4 . Here we show that multiply diffracted P waves along a stratified core–mantle boundary region of Mars in combination with first-principles computations of the thermoelastic properties of liquid iron-rich alloys 3 require the presence of a fully molten silicate layer overlying a smaller, denser liquid core. Inverting differential body wave travel time data with particular sensitivity to the core–mantle boundary region suggests a decreased core radius of 1,675 ± 30 km associated with an increased density of 6.65 ± 0.1 g cm −3 , relative to previous models 2,4–8 , while the thickness and density of the molten silicate layer are 150 ± 15 km and 4.05 ± 0.05 g cm −3 , respectively. The core properties inferred here reconcile bulk geophysical and cosmochemical requirements, consistent with a core containing 85–91 wt% iron–nickel and 9–15 wt% light elements, chiefly sulfur, carbon, oxygen and hydrogen. The chemical characteristics of a molten silicate layer above the core may be revealed by products of Martian magmatism.
Abstract Aim Pollination is an essential stage of angiosperm reproduction, and the mode of pollination plays a major role in driving evolutionary and ecological responses of plants to environmental changes. However, the effects of climate, evolutionary history and floral traits (i.e. plant sexual systems) on pollination mode variation remain unclear. Here, we explored the biogeographic patterns in pollination mode frequency and tested the hypothesis that insect pollination prevails in warm humid regions with old floras due to high pollinator dependence, whereas wind pollination is more frequent in arid regions with younger floras and is more strongly associated with dioecy. Location China. Time period Since the Last Glacial Maximum. Major taxa studied Angiosperms. Methods Using data on pollination modes and geographic ranges of 29,719 angiosperm species in China, we mapped the biogeographic pattern of pollination mode frequency. Phylogenetic logistic regressions and generalized linear mixed models were employed to evaluate the relative importance of climate, evolutionary history (represented by phylogenetic conservatism and grid-level mean genus age) and sexual systems on variations in pollination modes across species and space. Results Evolutionary history was the strongest correlate of pollination mode variation across species and space. The proportion of insect-pollinated species was higher in humid regions with old floras, but lower in arid regions with young floras. Evolutionary history and temperature dominated variations in pollination mode frequency in humid areas, while precipitation dominated in arid areas. Climate influenced geographic pattern in pollination mode frequency both directly and indirectly via its effects on species richness and plant sexual systems. Main Conclusions Our results showed that geographic pattern in angiosperm pollination mode frequency is dominated by evolutionary history followed by climate, which extended previous findings of climate-driven mechanisms. Our findings demonstrate the importance to incorporate evolutionary history in understanding the mechanisms underlying the functional biogeography of plant traits.
Abstract Aim Climate has been regarded as an important explanation for large-scale species richness patterns. However, the mechanisms underlying the significant variations in species richness?climate relationships across different clades remain to be tested. We explored how niche conservatism, diversification rates and time for speciation influenced species richness?climate relationships between clades. Location The globe. Time Period Present day. Major Taxa Studied Angiosperms. Methods Based on a newly complied database of the global distributions of 288,735 angiosperm species, we used generalized linear models to assess the relationships between species richness of different angiosperm families and climatic factors. We also conducted phylogenetic comparative analysis to test whether niche conservatism, diversification rates and time for speciation affect the variations in species richness?climate relationships. Results We found that temperature seasonality dominated the global angiosperm diversity patterns. Closely related families had more similar species richness?climate relationships than distantly related ones. The discrepancy between the current and ancestral niches of different clades had much stronger effects on variations in species richness?climate relationships than diversification rates and time for speciation. With the increase in the discrepancy between current and ancestral niches, the explanatory power (i.e., R2) of contemporary temperature and precipitation in explaining species richness patterns increased. Main Conclusions Overall, our findings strongly support that niche conservatism dominates the variations in species richness?climate relationships across taxonomic groups. These findings allow better understanding on how large-scale species diversity patterns are formed.
Organic aerosol particles are oxidized by atmospheric oxidants. These particles are occasionally internally mixed with solid materials such as soot and inorganic crystals. However, potential impacts of the particles' mixing states on chemical reactivity have rarely been investigated. This study investigated the influence of the existence of crystalline ammonium sulfate on chemical reactivity of oleic acid particles with ozone for the temperature range of −20°C to +35°C using an aerosol flow tube reactor. The chemical compositions of the resulting particles were monitored using online instruments for deriving the reactive uptake coefficients (γ) of ozone by oleic acid. The values of γ were not significantly influenced by the existence of ammonium sulfate when the temperature of the reactor was higher than the melting point of oleic acid (∼13°C). The values of γ were unmeasurably small for the lower temperature range when oleic acid particles were internally mixed with crystalline ammonium sulfate. No significant change in γ was observed for the temperature range down to −13°C when the inorganic salt was absent, likely due to the formation of supercooled liquid. The difference in chemical reactivity can be explained by the occurrence of heterogeneous nucleation induced by inorganic seed.
Abstract Organic aerosol particles are oxidized by atmospheric oxidants. These particles are occasionally internally mixed with solid materials such as soot and inorganic crystals. However, potential impacts of the particles' mixing states on chemical reactivity have rarely been investigated. This study investigated the influence of the existence of crystalline ammonium sulfate on chemical reactivity of oleic acid particles with ozone for the temperature range of −20°C to +35°C using an aerosol flow tube reactor. The chemical compositions of the resulting particles were monitored using online instruments for deriving the reactive uptake coefficients (γ) of ozone by oleic acid. The values of γ were not significantly influenced by the existence of ammonium sulfate when the temperature of the reactor was higher than the melting point of oleic acid (∼13°C). The values of γ were unmeasurably small for the lower temperature range when oleic acid particles were internally mixed with crystalline ammonium sulfate. No significant change in γ was observed for the temperature range down to −13°C when the inorganic salt was absent, likely due to the formation of supercooled liquid. The difference in chemical reactivity can be explained by the occurrence of heterogeneous nucleation induced by inorganic seed.
In the presence of the difficulties pertinent to the selective oxidation of cyanide and the high-efficient hydrolysis of cyanate, the mineralization of cyanide into nitrogen could not be realized during the traditional processes. Herein, a novel system of electrocatalysis coupled with ultraviolet-based advanced oxidation processes (UV/EC/PS, PS: persulfate) is developed, exhibiting astonishingly high activity and selectivity for cyanide mineralization. The achieved results reveal that adequate active-chlorine species (ClO•/Cl2•−) are generated due to the synergistic effects of electrocatalysis and advanced oxidation processes and these are high-selective for cyanide mineralization. Concurrently, induced by the interconversion between active species, the pH value in the UV/EC/PS system vigorously lessens from 11.5 to 3.3 at a rate of 1.1 × 10-2 min−1, hugely speeding up the hydrolysis of cyanate intermediates. The results display that PS plays a pivotal role in the formation of ClO•/Cl2•− and the self-reduction of pH value in the UV/EC/PS system. Under the action of ClO•/Cl2•− and self-decreased pH value, 0.25 mM of ferricyanide is thoroughly mineralized into nitrogen within 80 min and no HCN evolves. Additionally, the UV/EC/PS system exhibits exceptional feasibility for the practical purifications of cyanide-containing wastewater (CCWW). This study aims to give new insights into developing technologies associated with the mineralization treatment of CCWW.