Citation:
摘要:
The organic and inorganic species in total suspended particulates (TSP) collected from June to December in 1998 in Hong Kong were identified by gas chromatography-mass spectrometry (GC-MS) and inductively coupled plasma-mass spectrometry (ICP-MS) to investigate the sources of Hong Kong aerosols and the mechanisms that control the chemical compositions and variations in the atmosphere. These samples were classified according to the climate: wet, dry under the influence of southerly winds from the sea (Dry-S) and dry under the influence of northerly winds from the continent (Dry-N). There were significant increases of materials from crustal, biogenic and pollution sources in the Dry-N period by a factor of 5, 4, and 2, respectively. Since the crustal tracers (e.g., Al, Fe) could be from coal flyash, the estimate of crustal material in the Dry-N period may include some materials from pollution source. Therefore, a positive correlation between crustal and pollution elements was observed. From the analysis of solvent-extractable organics (SEOC), microbial and meat cooking sources showed slight increase (1.2-fold). Higher levels of plant wax materials in the Dry-N period were probably due to the higher wind speed during the winter monsoon. The percentage of crustal material in TSP was 47% in the Dry-N period, and only 22% in the wet season and the Dry-S period. Plant wax materials (biogenic source) had a higher percentage in the Dry-N period (39% of SEOC) while microbial and meat cooking sources accounted for 49% of SEOC in the wet season. This study revealed that wind direction and precipitation had a significant influence not only on the concentrations but also on the chemical compositions and sources of Hong Kong aerosols.