Improvement of Cs2AgBiBr6 double perovskite solar cell by rubidium doping

Citation:

Zhang Z, Wu C, Wang D, Liu G, Zhang Q, Luo W, Qi X, Guo X, Zhang Y, Lao Y, et al. Improvement of Cs2AgBiBr6 double perovskite solar cell by rubidium doping. ORGANIC ELECTRONICS. 2019;74:204-210.

摘要:

Cs2AgBiBr6 having a double perovskite structure is expected to achieve non-lead and stable optoelectronic devices, and has received wide attention recently. A strategy for improving of perovskite films via Rubidium cation (Rb+) is for the first time reported. When Rb+ was incorporated into Cs2AgBiBr6 to form (Cs1-xRbx)(2)AgBiBr6, the absorption at long wavelength was enhanced and the density of defect state was reduced without changing the crystal lattice. Furthermore, the mechanism of Rb+ doping to improve double perovskites and the optimal doping ratio was studied in this report. The average power conversion efficiency of doped devices is nearly 15% higher than that of standard devices from 20 devices of each group. Moreover, in the champion device, the power conversion efficiency achieved 1.52% with a high fill factory of 0.788.