Substantial biogenic secondary organic aerosol (BSOA) formation was investigated in a coniferous forest mountain region in Whistler, British Columbia. A largely biogenic aerosol growth episode was observed, providing a unique opportunity to investigate BSOA formation chemistry in a forested environment with limited influence from anthropogenic emissions. Positive matrix factorization of aerosol mass spectrometry (AMS) measurement identified two types of BSOA (BSOA-1 and BSOA-2), which were primarily generated by gas-phase oxidation of monoterpenes and perhaps sesquiterpenes. The temporal variations of BSOA-1 and BSOA-2 can be explained by gas-particle partitioning in response to ambient temperature and the relative importance of different oxidation mechanisms between day and night. While BSOA-1 arises from gas-phase ozonolysis and nitrate radical chemistry at night, BSOA-2 is likely less volatile than BSOA-1 and consists of products formed via gas-phase oxidation by OH radical and ozone during the day. Organic nitrates produced through nitrate radical chemistry can account for 22-33aEuro-% of BSOA-1 mass at night. The mass spectra of BSOA-1 and BSOA-2 have higher values of the mass fraction of m/zaEuro-91 (f(91)) compared to the background organic aerosol. Using f(91) to evaluate BSOA formation pathways in this unpolluted, forested region, heterogeneous oxidation of BSOA-1 is a minor production pathway of BSOA-2.
Vertical column densities (VCDs) of SO2 retrieved by a Pandora spectral sun photometer at Fort McKay, Alberta, Canada, from 2013 to 2015 were analysed. The Fort McKay site is located in the Canadian oil sands region, approximately 20 km north of two major SO2 sources (upgraders), with total emission of about 45 kt yr(-1). Elevated SO2 VCD values were frequently recorded by the instrument, with the highest values of about 9 Dobson Units (DU; DU = 2.69 x 10(16) molecules cm(-2)). Comparisons with co-located in situ measurements demonstrated that there was a very good correlation between VCDs and surface concentrations in some cases, while in other cases, elevated VCDs did not correspond to high surface concentrations, suggesting the plume was above the ground. Elevated VCDs and surface concentrations were observed when the wind direction was from south to southeast, i.e. from the direction of the two local SO2 sources. The precision of the SO2 measurements, estimated from parallel measurements by two Pandora instruments at Toronto, is 0.17 DU. The total uncertainty of Pandora SO2 VCD, estimated using measurements when the wind direction was away from the sources, is less than 0.26DU (1 sigma). Comparisons with integrated SO2 profiles from concurrent aircraft measurements support these estimates.
The self-assembly behaviors of two series of monodispersed oligomers consisting of perylenediimide (PDI) linked by ethynylene and butadiynylene spacers are investigated in solutions. In spite of the very similar chemical structures, the two sets of oligomers manifest completely different optical properties upon self-aggregation, implying differed aggregate structures. While the oligomers containing butadiynylene spacers form H-aggregates, those featuring ethynylene linkers display J-aggregation characteristics. Thermodynamic analysis revealed that the self-association constants of both series of oligomers increase with the number of PDI units in the backbones. Oligomers containing the same number of PDI units but different spacers display nearly identical enthalpy changes. According to the molecular exciton theory, the observed H-and J-aggregates are suggested to comprise similar packing motifs with slightly varied slipping angles, giving rise to greatly disparate optical properties.
Using readily available aryl glyoxylic acids and arylene diacetic acids as starting materials, a series of polycyclic aromatic molecules bearing two phthalimide functional groups are synthesized via Perkin condensation followed by intramolecular cyclization reactions. Two different cyclization methods, photo-oxidation and Heck cross-coupling, are employed, both of which effectively accomplish the transformations from diaryl maleic anhydride or maleimide to polycyclic aromatic phthalimide functionality. The photocyclization protocol conveniently allows direct bridging of two plain aromatic C-H sites linked by a maleic anhydride group and uniquely produces the more twisted polycyclic framework as the major product, whereas the Heck coupling approach can typically afford more extended polycyclic skeletons. Thionation reactions are then carried out for the obtained polycyclic diimide molecules using Lawesson's reagent. For all isolated stable products, partial thionation occurs. The prepared polycyclic diimide compounds possess relatively low LUMO levels, and thionation further decreases the LUMO energy of the molecules by 0.2-0.3 eV. Electron-transporting properties are characterized by using solution-processed OFET devices, and an electron mobility of 0.054 cm(2) V-1 s(-1) is demonstrated by a selected compound. Such semiconducting performance promises great potentials of this class of compounds as useful electron-accepting and transporting building blocks in developing various new semi-conductive materials.
To improve the efficiency of TiO<sub>2</sub> as a photocatalyst for contaminant degradation, a novel nanocomposite catalyst of (N, Fe) modified TiO<sub>2</sub> nanoparticles loaded on bentonite (B-N/Fe-TiO<sub>2</sub>) was successfully prepared for the first time by sol-gel method. The synthesized B-N/Fe-TiO<sub>2</sub> catalyst composites were characterized by multiple techniques, including scanning electron microscope (SEM), energy dispersive spectrometry (EDS), X-ray diffraction (XRD), Fourier transform infrared spectra (FT-IR), X-ray fluorescence (XRF), nitrogen adsorption/desorption, UV-Vis diffuse reflectance spectra (DRS), and electron paramagnetic resonance (EPR). The results showed that bentonite significantly enhanced the dispersion of TiO<sub>2</sub> nanoparticles and increased the specific surface area of the catalysts. Compared with nondoped TiO<sub>2</sub>, single element doped TiO<sub>2</sub>, or unloaded TiO<sub>2</sub> nanoparticles, B-N/Fe-TiO<sub>2</sub> had the highest absorption in UV-visible region. The photocatalytic activity of B-N/Fe-TiO<sub>2</sub> was also the highest, based on the degradation of methyl blue (MB) at room temperature under UV and visible light irradiation. In particular, the synthesized B-N/Fe-TiO<sub>2</sub> showed much greater photocatalytic efficiency than N/Fe-TiO<sub>2</sub> under visible light, the newly synthesized B-N/Fe-TiO<sub>2</sub> is going to significantly increase the photocatalytic efficiency of the catalyst using sun light.
Abstract Human activities are the main drivers of alterations of regional N cycles. With increasing population and economic development, human-induced N inputs are expected to continue to increase in the future, especially in many regions of developing countries. Because N sources vary substantially at different temporal and spatial scales and stages of economic development, it is of great importance for environmental managers to be able to simulate the dynamics of N inputs to a specific region of interest. Based on the concept of net anthropogenic N inputs (NANI), a quasi-mass-balance method, a system dynamics model simulating regional N inputs (NANI-SD) is developed and presented here for the first time. The NANI-SD model evaluates how much new N from anthropogenic activities is introduced to the whole basin, providing a simple but effective way to examine human influences on regional N cycles. Our application of the NANI-SD model to the Lake Dianchi basin in China shows that human-induced N inputs will continue to increase under current trends of development. Scenarios focused on lowering population growth rate and banning crop production were not effective in achieving long-term reductions in N inputs because their impacts were compensated by the increases in croplands and food imports, respectively. However, adjusting diet patterns and limiting livestock numbers within the basin were shown to be highly effective in controlling regional N inputs without compromising environmental sustainability of food imported regions. There was a significant trade-off between N self-sufficiency and N inputs to the region, posing the issue of “pollution transfer” as the regions of livestock production providing animal products to the Lake Dianchi basin could suffer from locally intensified levels of N pollution introduced while producing those animal N products. The positive relationship between NANI and the proportion of animal-based protein in food indicates that reducing meat consumption could be an effective way of controlling local N inputs without sacrificing food sovereignty. NANI to the basin could also be reduced by recycling N in human and livestock wastes, but its capacity to reduce NANI is limited and projected to diminish with time.