科研成果

2021
Cai W, Zhang C, Suen HP, Ai S, Bai Y, Bao J, Chen B, Cheng L, Cui X, Dai H, et al. The 2020 Chinese Report of The Lancet Countdown on Health and Climate Change. The Lancet Public Health [Internet]. 2021;6:e64-e81. 访问链接
Cai W, Zhang C, Zhang S, Ai S, Bai Y, Bao J, Chen B, Chang N, Chen H, Cheng L, et al. The 2021 China Report of The Lancet Countdown on Health and Climate Change. The Lancet Public Health [Internet]. 2021;6:e932-e947. 访问链接
\textbfShen \textbfL, Gao Z, Yang X, Shi W, Sun N. [2021.ISSCC].27.7 A 79dB-SNDR 167dB-FoM Bandpass ΔΣ ADC Combining N-Path Filter with Noise-Shaping SAR, in 2021 IEEE International Solid- State Circuits Conference (ISSCC).Vol 64.; 2021:382-384.
KUANG Y, CUI X, ZHONG Y, LIU K, ZOU C, DAI Z, Wang Y, YU D, HUANG R. A 64K-neuron 64M-synapse 2.64pJ/SOP Neuromorphic Chip with All Memory on Chip for Artificial General Intelligence in 65nm CMOS. IEEE Transactions on Circuit and Systems II: Brief Paper [Internet]. 2021;68(7):2655-2659. 访问链接Abstract
Generally, computer-science-oriented artificial neural networks (ANNs) and neuroscience-oriented spiking neural networks (SNNs) are two main approaches to develop brainspired non von Neumann computing systems. The goal of exploring complex artificial intelligence (AI) systems demandsgeneral neuromorphic hardware platforms compatible with both of them. However, as a result of the obvious differences in their fundamental mathematical expression and coding scheme, many neuromorphic platforms or deep neural network (DNN) accelerators accommodate only one of them. This brief presents a reconfigurable scalable neuromorphic chip based on digital leaky integrate-and-fire (LIF) neuron model targeting low-cost large-scale systems. By unifying ANN and SNN paradigms within a LIF neuron framework with point-to-point (P2P) communication, the chip can accommodate most popular neural networks. The chip adopts distributed on-chip memory architecture with a capacity of 64K neurons and 64M synapses. It achieves a peak throughput of 12.29 GSOP/s at 1.2 V, 192MHz and peak energy efficiency of 2.64 pJ/SOP at 890 mV, 24MHz.The results of implementations of a spike-based spatio-temporal memory model and ternary-weight event-based convolutional neural networks (CNNs) demonstrate outstanding compatibility of the chip.
周智健, 王信, 常剑, 陈宏刚, 牛玉广. 660MW燃煤电厂SCR脱硝系统CFD模拟优化研究. 中国电机工程学报 [Internet]. 2021;41(19):6688-6699. 访问链接Abstract
为探究流场和组分浓度分布对SCR装置脱硝效率和氨逃逸的影响进而提升脱硝性能,基于ANSYS FLUENT软件平台、耦合多孔介质模型和E-R脱硝反应动力学模型,建立国内某660 MW燃煤机组SCR系统的三维计算流体力学模型;详细分析不同负荷下烟气速度分布、组分浓度分布、脱硝效率和氨逃逸等流动反应特性;进而针对分区喷氨和静态混合器对脱硝性能的影响进行模拟与优化。结果表明:当顶部导流板倾角与楔形弯头倾角相同时,流场分离现象消失,速度分布更加均匀。较之于均匀喷氨方式,分区喷氨可使NH_3浓度均匀性提高55%、出口NO浓度偏差降低50%。采用平板型混合器结合分区喷氨策略,催化剂入口截面NH3浓度偏差系数小于2.5%,出口截面NO浓度偏差系数小于8%,局部最大氨逃逸为1.82mg/m~3,脱硝效率提高了7%,实现SCR装置的稳定高效运行。
Mukherjee A, Gandara M, Yang X, Shen L, TANG X, Hsu C-K, Sun N. A 74.5-dB Dynamic Range 10-MHz BW CT-ΔΣ ADC With Distributed-Input VCO and Embedded Capacitive-π Network in 40-nm CMOS. IEEE Journal of Solid-State Circuits. 2021;56:476-487.Abstract
This work introduces a second-order voltage-controlled oscillator (VCO)-based continuous-time delta-sigma modulator (CTDSM) that incorporates a distributed-input VCO as the second-stage integrator and quantizer. The distributed-input VCO topology virtually eliminates the VCO's voltage-to-frequency (V-F) parasitic pole. One of the key ideas of this article is to demonstrate the use of a capacitive-π network in the modulator's loop filter to break the constraint between the size of the modulator's inner capacitive digital-to-analog converter (DAC) and the factor by which the front-end Gm-C integrator is impedance scaled. This, in turn, helps to significantly reduce both analog and digital powers. The prototype chip has been fabricated in a 40-nm CMOS process. Despite not using any DAC calibration or explicit dynamic element matching (DEM) circuits, the worst case spurious-free dynamic range (SFDR) is -82 dBc across the signal bandwidth. The fabricated CTDSM achieves a 71.8-dB signal-to-noise-and-distortion ratio (SNDR) and a 74.5-dB dynamic range (DR) in a 10-MHz bandwidth at 655 MS/s, yielding an SNDR-based Walden figure of merit (FoM) of 45.6 fJ/step, an SNDR-based Schreier FoM of 167.2 dB, and a DR-based Schreier FoM of 169.9 dB.
Lai L, Ji H, Zhang H, Liu R, Zhou C, Liu W, Ao Z, Li N, Liu C, Yao G, et al. Activation of peroxydisulfate by V-Fe concentrate ore for enhanced degradation of carbamazepine: Surface ≡V(III) and ≡V(IV) as electron donors promoted the regeneration of ≡Fe(II). Applied Catalysis B: Environmental [Internet]. 2021;282:119559. 访问链接Abstract
V-Fe concentrate ore was applied to activate peroxydisulfate (PDS) for carbamazepine (CBZ) degradation. The excellent performance of V-Fe concentrate ore was mainly ascribed to the quick electron transfer from surface ≡V(III) and ≡V (IV) to ≡Fe(III) for ≡Fe(II) regeneration, which was confirmed by XPS and XAS analyses. This accelerated ≡Fe(II) regeneration could thus lead to quick formation of HO, SO4−, O2− and effective degradation of CBZ. The degradation rate of CBZ could be also expressed by a kinetic model, i.e., −d[CBZ]/dt = (0.83 mM-0.55 min-1(g/L)-0.65) [CBZ]0.29[PDS]1.26[V-Fe]0.65. Combined with the measured intermediates and the results of DFT calculation, CBZ degradation pathway was proposed systematically. Moreover, this catalyst displayed excellent recyclability and general applicability for a broad substrate scope. This study suggests low valent vanadium makes crucial contributions to the high activity of V-Fe-based catalysts, and improves the understanding of electron transfer mechanism between V and Fe in PDS activation process.
Zhao Z, Zhang W, Liu W, Li Y, Ye J, Liang J, Tong M. Activation of sulfite by single-atom Fe deposited graphitic carbon nitride for diclofenac removal: The synergetic effect of transition metal and photocatalysis. Chemical Engineering Journal [Internet]. 2021;407:127167. 访问链接Abstract
Herein, through supramolecular gel assisted pre-configuration, a novel bamboo-like porous graphitic carbon nitride (g-C3N4) deposited with single-atom Fe was successfully prepared and used for sulfite (S(IV)) activation. Unexpectedly, owing to the presence of single-atom Fe, hybrid material with only 2.5‰ of Fe exhibited 16 times higher S(IV) activation efficiency for diclofenac removal than pure g-C3N4 under visible light irradiation. Moreover, a synergetic effect of Fe and g-C3N4 was found to play the dominate role, and the synergetic factor was calculated to be 0.84. The synergetic mechanism mainly related to the generation of surface Fe-S(IV) complex, which could be affected by S(IV) species or the presence of H2PO4−. DCF removal was significantly enhanced at alkaline condition, but the enhancement was mainly attributed to photocatalysis but not synergetic effect. Decarboxylation, hydroxylation, chlorine abstraction and cleavages at bridging N atom were the main degradation pathways of DCF, which agreed well with Fukui index prediction. The toxicity of DCF was alleviated during the degradation process through successful mineralization of chlorine atoms.
Arellano-Gonzalez J, AghaKouchak A, Levy MC, Qin Y, Burney JA, Davis SJ, Moore FC. The adaptive benefits of agricultural water markets in California. Environmental Research Letters. [Internet]. 2021;16(044036). 访问链接
Li M, Ao Y, Yang C. Adaptive SpMV/SpMSpV on GPUs for Input Vectors of Varied Sparsity. IEEE Transactions on Parallel and Distributed Systems [Internet]. 2021;32(7):1558-2183. 访问链接
Deng H, Navarre-Sitchler A, Heil E, Peters C. Addressing water and energy challenges with reactive transport modeling. Environmental Engineering Science. 2021;38:109–114.
Zhu Y, Xu T, Zhao D, Li F, Liu W, Wang B, An B. Adsorption and solid-phase photocatalytic degradation of perfluorooctane sulfonate in water using gallium-doped carbon-modified titanate nanotubes. Chemical Engineering Journal [Internet]. 2021;421:129676. 访问链接Abstract
Perfluorooctane sulfonate (PFOS) has drawn increasing attention due to its omnipresence and adverse health effects. We prepared a new adsorptive photocatalyst, Ga/TNTs@AC, based on activated carbon and TiO2, and tested the adsorption and subsequent solid-phase photodegradation of PFOS. Ga/TNTs@AC showed faster adsorption kinetics and higher affinity for PFOS than the parent AC, and could degrade 75.0% and mineralize 66.2% of pre-sorbed PFOS within 4-h UV irradiation. The efficient PFOS photodegradation also regenerates Ga/TNTs@AC, allowing for repeated uses without invoking chemical regenerants. The superior photoactivity is attributed to the oxygen vacancies, which not only suppressed recombination of the e−/h+ pairs, but also facilitated O2− generation. Both h+ and O2− played critical roles in the PFOS degradation, which starts with cleavage of the sulfonate group and converts it into PFOA that is then decarboxylated and defluorinated following the stepwise defluorination mechanism. Ga/TNTs@AC holds the potential for more cost-effective PFOS degradation.
Ji H, Wang T, Huang T, Lai B, Liu W. Adsorptive removal of ciprofloxacin with different dissociated species onto titanate nanotubes. Journal of Cleaner Production [Internet]. 2021;278:123924. 访问链接Abstract
Exploring the specific characteristics of pharmaceuticals and personal care products (PPCPs) via adsorption and degradation are scientific and practical significance to control their release to water matrix. In this work, a good adsorbent and ion-exchange material, i.e., titanate nanotubes (TNTs), was employed for adsorption of ciprofloxacin (CIP, a model PPCPs). The adsorption behaviors and mechanisms of CIP with different dissociated species by TNTs were studied through both experimental and theoretical calculations. The multilayered TNTs with high BET surface area (272.3 m2/g) and large pore volume (1.26 cm3/g) exhibited good adsorption property for CIP. The CIP species (i.e., CIP+, CIP±, CIP−) at various pH exhibited significantly different adsorption favorability. Adsorption kinetics and isotherms data revealed that TNTs offered the high uptake for CIP+ (Qmax = 464.47 μmol/g or 153.90 mg/g at pH 5) than CIP± and CIP−. Characterizations indicated the formation of Ti−O−N linkage between CIP molecules and TNTs after adsorption, suggesting the chemical interaction between CIP and TNTs. Density functional theory (DFT) calculations reveal variation on pH affects the protonation/deprotonation state of CIP, and then changes the distribution of molecular orbitals and the electrostatic potential (ESP) energy of CIP. ESP follows the trend as: CIP+ (180.57 kcal/mol) > CIP± (146.78 kcal/mol) > CIP− (12.30 kcal/mol), indicating the side of piperazine ring in CIP oriented to TNTs dominates the CIP adsorption. The integrated experimental and theoretical results, for the first time, suggest that ESP energy can serve as the indicator and predictor of adsorption ability for the PPCPs molecules with various speciation, and can help to deeply describe the adsorption mechanism of PPCPs. In addition, TNTs have great application for the removal of PPCPs through adsorption in practical wastewater treatment area.
Ji H, Wang T, Huang T, Lai B, Liu W. Adsorptive removal of ciprofloxacin with different dissociated species onto titanate nanotubes. Journal of Cleaner Production. 2021;278:123924.
Kong L, Hadavimoghaddam F, Li C, Liu K, Liu B, Semnani A, Ostadhassan M. AFM vs. Nanoindentation: Nanomechanical properties of organic-rich Shale. Marine and Petroleum Geology [Internet]. 2021;132:105229. 访问链接Abstract
Obtaining elastic properties of organic-rich shales through conventional geomechanical testing could be challenging due to availability of good quality core plugs and significant heterogeneous nature of the samples. In this regard, force spectroscopy methods, nanoindentation and atomic force microscopy (AFM) are two main powerful techniques to characterize elastic properties in nano/microscale. In this study, we investigate the applicability of these two methods on the same samples, by quantifying elastic modulus from the Bakken Shale. AFM provided us with modulus maps of higher resolution compared to the modulus maps from the nanoindentation that were created via geostatistical methods. Moreover, results from these methods were compared to demonstrate the advantages and shortcomings of each and discripancy in the outcome. To do so, multi-cluster deconvolution approach was adopted in the statistical analysis on the nanoindentation data, demonstrating 3 separate clusters and mechanical phases. AFM technique, similarly, distinguished three separate (mineral and organic) phases based on the corresponding modulus values, though with higher accuracy compared to nanoindentation and better distinction and less tolerance. It was found that nanoindentation, because it collects discrete datapoints that are farther apart from each other when thermal maturity is increased in the samples, would have difficulty to separate organic matter from intermediary phases. Overall, the range of modulus for each phase was larger in the data that was obtained by nanoindentation compared to the AFM which can be interpreted to the size of the tip and general higher resolution in the later one which is expected to probe a single particle rather than an aggregate of particles.
AgI modified covalent organic frameworks for effective bacterial disinfection and organic pollutant degradation under visible light irradiation. Journal of Hazardous Materials [Internet]. 2021. 访问链接
Wang Y, Fu X, Wu D, Wang M, Lu K, Mu Y, Liu Z, Zhang Y, Wang T. Agricultural Fertilization Aggravates Air Pollution by Stimulating Soil Nitrous Acid Emissions at High Soil Moisture. Environmental Science & Technology. 2021;55.
Li D, Overeem I, Kettner AJ, Zhou Y, Xixi L. Air temperature regulates erodible landscape, water and sediment fluxes in the permafrost-dominated catchment on the Tibetan Plateau. Water Resources Research [Internet]. 2021;57:e2020WR028193. 访问链接Abstract
AbstractApproximately 40% of the Tibetan Plateau (TP) is underlain by continuous permafrost, yet its impact on fluvial water and sediment dynamics remains poorly investigated. Here we show that water and sediment dynamics in the permafrost-dominated Tuotuohe basin on the TP are driven by air temperature and permafrost thaw, based on 33-year daily in-situ observations (1985-2017). Air temperature regulates the seasonal patterns of discharge and suspended sediment concentration (SSC) by controlling the changes in active contributing drainage area (ACDA, the unfrozen erodible landscape that contributes hydrogeomorphic processes within a catchment) and governing multiple thermal processes such as glacier-snow melt and permafrost thaw. Rainstorms determine the short-lived fluvial extreme events by intensifying slope processes and channel erosion and likely also by enhancing thaw slumps. Furthermore, the SSCs at equal levels of discharges are lower in autumn (September-October) than in spring (May-June) and summer (July-August). This reduced sediment availability in autumn can possibly be attributed to the increased supra-permafrost groundwater runoff and the reduced surface runoff and erosion. Due to rapid climate warming, the ACDA has increased significantly from 1985 to 2017, implying expanding landscapes for hydrogeomorphic processes. As a result, the fluvial water and sediment fluxes have substantially increased. In a warmer and wetter future for the TP, the fluvial sediment fluxes of similar permafrost-underlain basins will continue to increase with expanding erodible landscapes and intensifying thermal and pluvial-driven geomorphic processes. Thus, permafrost thaw should be considered as an important driver of past and future water and sediment changes for the TP.This article is protected by copyright. All rights reserved.
Baug T, Wang K, Liu T, Wu Y-F, Di Li, Zhongshi Wang, Zhang Q, Tang M, Goldsmith PF, Liu H-L, Tej A, et al. An ALMA study of outflow parameters of protoclusters: outflow feedback to maintain the turbulence. \mnras. 2021;507:4316-4334.
Barnes A  T, Henshaw J  D, Fontani F, Pineda J  E, Cosentino G, Tan J  C, Caselli P, Jiménez-Serra I, Law C  Y, Avison A, et al. ALMA-IRDC: dense gas mass distribution from cloud to core scales. \mnras. 2021;503:4601-4626.

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