To ensure safe and efficient geologic CO2 sequestration (GCS), it is crucial to have a better understanding of CO2–brine–rock interactions under GCS conditions. In this work, using biotite (K(Mg,Fe)3AlSi3O10(OH,F)2) as a model clay mineral, brine-biotite interactions were studied under conditions relevant to GCS sites (95 °C, 102 atm CO2, and 1 M NaCl solution). After reaction for 3–17 h, fast growth of fibrous illite on flat basal planes of biotite was observed. After 22–70 h reaction, the biotite basal surface cracked, resulting in illite detaching from the surface. Later on (96–120 h), the cracked surface layer was released into solution, thus the inner layer was exposed as a renewed flat basal surface. The cracking and detachment of the biotite surface layer increased the surface area in contact with solution and accelerated biotite dissolution. On biotite edge surfaces, Al-substituted goethite and kaolinite precipitated. In control experiments with water under the same temperature and pressure, neither macroscopic fibrous illite nor cracks were observed. This work provides unique information on biotite-brine interaction under acidic hydrothermal conditions.
A dielectric-film-coated asymmetric single nanoslit is proposed to realize broadband unidirectional generation of surface plasmon polaritons (SPPs). Due to the tight field confinements by the dielectric film and the deep groove in the asymmetric single slit, the transmittance of the SPPs in the groove to the left side considerably decreases. This greatly suppresses the left-propagating SPP generation efficiency for a broad bandwidth. Meanwhile, the right-propagating SPP generation efficiency has a flat spectra range because of the low transmittance, too. So the unidirectional SPP generation with bandwidth of > 100 nm around lambda = 750 nm is experimentally achieved for the device lateral dimension of only 865 nm. (C) 2011 Optical Society of America