Persistent green innovation helps enterprises save energy, reduce pollution, and continue to gain economic benefits. However, existing studies explored the economic and organizational factors influencing firms’ persistent green innovation while neglecting peer influence in the digital economy. This study examines the impact of digital economy and peer influence on persistent green innovation using data of Chinese-listed companies from 2011 to 2019. The results show that digital economy and peer influence positively affect persistent green innovation. Moreover, digital economy plays a competitive mediating role between peer influence and persistent green innovation. The results of further research show that both the time lag term of peer influence and spatial lag term of digital economy affect persistent green innovation. This study incorporates the three-level elements of enterprise, peer, and city into a unified framework, providing theoretical reference and practical guidance for green innovation to enhance the competitive advantage of enterprises.
There is growing interest in the relationship between digitalization and environmental, social, and governance (ESG) performance, but existing research focuses on the one-way relationship and ignores the two-way mechanism. Based on a sample of 3335 listed companies in China in 2020, this study adopts a spatial simultaneous equation model to investigate the bidirectional mechanism between companies’ digitalization and ESG performance. The results show that digitalization and ESG performance have a significant positive two-way mechanism; digitalization enhances ESG performance, while ESG performance promotes digitalization. The results also indicate a significant positive intra-industry spillover effect for both digitization and ESG performance. Further research shows that the relationship between digitization and ESG performance does not differ depending on the definition of spatial weights, however, the spillover effects do differ depending on the definition of spatial weights.
Microplastics, recognized as some of the most pervasive and enduring pollutants, have emerged as a potential threat to environmental eco-health. While much is known about the effects of microplastics on soil microorganisms, our understanding of how they interact with terrestrial organisms and the underlying mechanisms remains limited. In this study, the effects of polyethylene microplastics at a concentration of 0.5 % (w/w) on the antioxidant enzymes, gut microbiota of Eisenia fetida and the soil microbiota on days 1, 3, 7, 15, and 30 were investigated. The results indicated that exposure to microplastics slightly increased the activities of superoxide dismutase (1.22-fold on day 3, 1.12-fold on day 7) and catalase (1.10-fold on day 3, 1.09-fold on day 7) in E. fetida, while exposure markedly decreased peroxidase activity (1.33- to 1.79-fold) throughout the whole period. Both the soil microbiota and the gut microbiota of E. fetida in terms of diversity and composition were significantly affected by the microplastic amendment, and their structure tended to be similar throughout the exposure time. The family Nocardiaceae was significantly enriched in both the soil and E. fetida gut biota with microplastic exposure. Our results demonstrated that the antioxidant enzyme response of E. fetida was closely related to both the microbiota, although this relationship with the gut microbiota may have been weakened by microplastic exposure. Overall, this study furnishes new perspectives on the ecotoxicity of microplastics, revealing significant implications for the vitality of soil-dwelling organisms and the overarching health of terrestrial ecosystems.
A visa-free policy is a tool for attracting foreign tourists, but existing studies evaluating its effects do not consider spatial spillover. This study, therefore, examined the effects of visa policies on urban inbound tourism with spatial spillover. This study used the implementation of the 72-hr visa-free transit policy in China as a natural experiment and employed a spatial difference-in-differences approach. The results show that the implementation of the 72-hr visa-free transit policy had no significant effect on the number of foreign tourists, but can reduce the average length of stay for foreign tourists. It also shows that there is a significant spatial spillover effect on the flow of foreign tourists. The results indicate the importance of spatial spillover in the evaluation of the impact of visa policy on inbound tourism, providing empirical evidence for further improving visa-free policies and urban tourism development.
Mega-events such as the Olympic Games, the World Cup, the World Expos, and the G20 Summit play important roles in international political economy in the age of globalization. But we know little about how they shape domestic politics and policy processes in their host countries. China has emerged as the leading host of various sports, cultural, economic, and political mega-events in the past decades. Employing an original panel dataset of Chinese cities from 2001 to 2019, we find that cities that host mega-events gain an advantage in bargaining with central bureaucracies for policy resources. Using subway investments as an example, we demonstrate that host cities not only obtained centrally regulated infrastructure investments that directly serve the needs of the events, but also achieve development that they otherwise could not. The result is robust with two-way fixed effects models and after accounting for various alternative explanations. We show that host cities gain advantage because the events capture the attention of national leaders. National leaders have power over central bureaucrats’ careers and thus steer their decisions, and they see the success of mega-events as an opportunity to project national strengths. Our findings highlight the domestic policy consequences of international events in the age of China’s rapid rise and integration with the world.
Populism has recently enjoyed success in Europe, the US, and beyond. Populist leaders and their supporters have accused “mainstream” media of being part of a “corrupt” elite that misrepresents the will of the virtuous “people.” Distrust of the media has also prompted the rejection of traditional media sources for political information and given prominence to alternative and hyperpartisan sources such as Breitbart. However, limited research exists concerning who consumes hyperpartisan media, how the websites of hyperpartisan media are interconnected, and what content is presented in hyperpartisan news. By combining cross-national surveys with large-scale digital trace datasets of website visits, this paper demonstrates the link between populist party support and hyperpartisan media visits. It also identifies influential sources of hyperpartisan news by analyzing the audience similarity networks of these websites and reveals country-level variations in hyperpartisan news and the dominance of US politics among the identified hyperpartisan news topics.
Financial inclusion and energy poverty have an interactive relationship; however, this two-way relationship lacks sufficient research. This study investigates the two-way mechanisms of financial inclusion, energy poverty, and neighborhood spillover effects. Using a spatial simultaneous equation model, this study examines 2615 Chinese rural households in 2020. Results reveal a statistically significant positive interaction between financial inclusion and energy poverty. In addition, the neighborhood spillover effects of financial inclusion and energy poverty are both significantly positive, whereas their neighborhood interaction spillover effects are significantly negative.
Using 13,584 observations of 4772 undergraduate students enrolled in 523 online classes offered synchronously at a research university in China, and using online-learning platform data and administrative data, this paper examines the impacts of class attendance on academic performance. Based on student-level and course-level fixed effects models with a unique set of student-course level control variables, this paper finds class attendance to have a significantly positive impact on academic performance. This effect is larger for low-performing students and smaller for students in courses with larger class sizes. The above findings survive a number of robustness checks, including a bounding technique, restricting sample to compulsory courses and limiting variation in attendance caused by whole day absence.
Abstract The insufficient exciton (e−-h+ pair) separation/transfer and sluggish two-electron water oxidation are two main factors limiting the H2O2 photosynthetic efficiency of covalent organic frameworks (COFs) photocatalysts. Herein, we present an alternative strategy to simultaneously facilitate exciton separation/transfer and reduce the energy barrier of two-electron water oxidation in COFs via a dicyano functionalization. The in situ characterization and theoretical calculations reveal that the dicyano functionalization improves the amount of charge transfer channels between donor and acceptor units from two in COF-0CN without cyano functionalization to three in COF-1CN with mono-cyano functionalization and four in COF-2CN with dicyano functionalization, leading to the highest separation/transfer efficiency in COF-2CN. More importantly, the dicyano group activates the neighbouring C atom to produce the key *OH intermediate for effectively reducing the energy barrier of rate-determining two-electron water oxidation in H2O2 photosynthesis. The simultaneously enhanced exciton separation/transfer and two-electron water oxidation in COF-2CN result in high H2O2 yield (1601 μmol g−1 h−1) from water and oxygen without using sacrificial reagent under visible-light irradiation. COF-2CN can effectively yield H2O2 in water with wide pH range, in different real water samples, in scaled-up reactor under natural sunlight irradiation, and in continuous-flow reactor for consecutively producing H2O2 solution for water decontamination.
Human occupants themselves constitute an important source of volatile organic compounds (VOCs) in indoor environments through breath and dermal emissions. In order to quantify VOC emissions from occupants under real-world settings, previous indoor observational studies often determined emission factors (i.e., average emission rates per person). However, the values obtained across these studies exhibited large variability, and the causes of this variability still need to be understood. Herein we report 10-day real-time VOC measurements in a university student office, using a proton transfer reaction-quadrupole interface-time-of-flight mass spectrometer. A method was developed to identify VOCs of primary human origin and to quantify the corresponding emission factors, accounting for the dynamically changing occupancy level and ventilation rate in the assessed office. We found that the emission factors of many dermally emitted VOCs strongly increased as the ozone concentration increased from <3 to 10–15 ppb. These VOCs include geranyl acetone, 6-methyl-5-hepten-2-one (6-MHO), and C10-C12 saturated aldehydes, which align with characteristic first-generation ozonolysis products of skin oil. The strongest increase occurred for 6-MHO, from 113 to 337 μg/h/p. In comparison, acetone and isoprene, which are primarily emitted from human breath, varied little with the ozone level. In light of this finding, we conducted an integrated analysis of emission factors reported in the literature for two frequently reported species, namely, 6-MHO and decanal. Ozone concentration alone can explain 94–97% of the variation in their emission factors across previous studies, and the best-estimated ozone dependence obtained using the literature data is consistent with those obtained in the current study. These results suggest that the ozone concentration is a key factor regulating emission factors of many dermally emitted VOCs in real indoor environments, which has to be considered when reporting or using the emission factors.
Quorum sensing (QS)-based manipulations emerge as a promising solution for biofilm reactors to overcome challenges from inefficient biofilm formation and lengthy start-ups. However, the ecological mechanisms underlying how QS regulates microbial behaviors and community assembly remain elusive. Herein, by introducing different levels of N-acyl-homoserine lactones, we manipulated the strength of QS during the start-up of moving bed biofilm reactors and compared the dynamics of bacterial communities. We found that enhanced QS elevated the fitness of fast-growing bacteria with high ribosomal RNA operon (rrn) copy numbers in their genomes in both the sludge and biofilm communities. This led to notably increased extracellular substance production, as evidenced by strong positive correlations between community-level rrn copy numbers and extracellular proteins and polysaccharides (Pearson's r = 0.529−0.830, P < 0.001). Network analyses demonstrated that enhanced QS significantly promoted the ecological interactions among taxa, particularly cooperative interactions. Bacterial taxa with higher network degrees were more strongly correlated with extracellular substances, suggesting their crucial roles as public goods in regulating bacterial interactions and shaping network structures. However, the assembly of more cooperative communities in QS-enhanced reactors came at the cost of decreased network stability and modularity. Null model and dissimilarity-overlap curve analysis revealed that enhanced QS strengthened stochastic processes in community assembly and rendered the universal population dynamics more convergent. Additionally, these shaping effects were consistent for both the sludge and biofilm communities, underpinning the planktonic-to-biofilm transition. This work highlights that QS manipulations efficiently drive community assembly and confer specialized functional traits to communities by recruiting taxa with specific life strategies and regulating interspecific interactions. These ecological insights deepen our understanding of the rules governing microbial societies and provide guidance for managing engineering ecosystems.
The speedy raise of residential buildings' carbon emissions is a hindrance to achieving China's 2030 carbon peak goal. This study constructs an assessment framework for comprehensive consideration of 30 Chinese provinces' socioeconomic circumstances, energy demand, and emissions reduction technology to meet the consistent coupling degree of equity and efficiency (CDEE). This study is the first to propose an allocation scheme for equilibrating provincial carbon increments for rural and urban residential buildings in 2030 under carbon peaking constraints. The relevant results are fourfold. (1) Residential building's floor area per capita and energy carbon emissions coefficients are the soliddest drivers to facilitate and inhibit the raise of carbon emissions during 2010–2020. (2) Through dynamic Monte Carlo simulation from 2021 to 2030, we demonstrate that provinces with the most gamey carbon emissions in urban and rural areas include Shandong, at 121.52 (± 5.50) Mt. and Hebei, at 61.34 (± 3.08) Mt. in 2030, respectively. (3) A CDEE of 52.3% (biased equity) in urban areas and 34.5% (biased efficiency) in rural areas indicates equilibrated allocation of provincial carbon increment. (4) In the final 2030 allocation scheme, the greatest carbon mitigation pressures are in Beijing (11.34 Mt) and Heilongjiang (3.23 Mt), and the provinces with the largest carbon increment in urban areas include Hebei, Henan, and Guangdong, while the largest carbon increments in rural areas are in Hebei, Henan, and Guangdong. Overall, this study furnishes a targeted and valuable decision making reference for the government to determine provincial carbon peak goals for Chinese residential buildings.
Chlorinated paraffins (CPs), mainly short-chain CPs (SCCPs) and medium-chain CPs (MCCPs), are currently the most produced and used industrial chemicals related to persistent organic pollutants (POPs) globally. These chemicals are widely detected in the environment and in the human body. As the release of SCCPs and MCCPs from products represents only a small fraction of their stock in products, the potential long-term release of CPs from a large variety of products at the waste stage has become an issue of great concern. The results of this study showed that, by 2050, SCCPs and MCCPs used between 2000 and 2021 will cumulatively generate 226.49 Mt of CP-containing wastes, comprising 8610.13 kt of SCCPs and MCCPs. Approximately 79.72 Mt of CP-containing wastes is predicted to be generated abroad through the international trade of products using SCCPs and MCCPs. The magnitude, distribution, and growth of CP-containing wastes subject to environmentally sound disposal will depend largely on the relevant provisions of the Stockholm and Basel Conventions and the forthcoming global plastic treaty. According to multiple scenarios synthesizing the provisions of the three conventions, 26.6–101.1 Mt of CP-containing wastes will be subject to environmentally sound disposal as POP wastes, which would pose a great challenge to the waste disposal capacity of China, as well as for countries importing CP-containing products. The additional 5-year exemption period for MCCPs is expected to see an additional 10 Mt of CP-containing wastes subject to environmentally sound disposal. Thus, there is an urgent need to strengthen the Stockholm and Basel Conventions and the global plastic treaty.
This paper aims to examine the impact of the digital economy on urban entrepreneurship and its spatial spillover effects. To achieve this purpose, this research relies on data from 252 prefecture-level cities in China from 2012 to 2019. The findings demonstrate that the development of the digital economy has a positive influence on entrepreneurial activity in cities, with particularly effects observed robust at higher quantile levels. Additionally, the results suggest that urban entrepreneurial activity may be a siphoning effect, impeding entrepreneurship in neighboring cities. Furthermore, further investigation shows regional and policy heterogeneity.
