摘要:

The high efficiency of perovskite solar cells benefits from the high density of photoinduced free carriers. We studied how exciton and free carriers, as the two major photoproducts, coexist inside the CH3NH3PbI3 perovskite. A new density-resolved spectroscopic method was developed for this purpose. The density-dependent coexistence of excitons and free carriers over a wide density range was experimentally observed. The quantitative analysis on the density-resolved spectra revealed a moderate exciton binding energy of 24 +/- 2 meV. The results effectively proved that the strong ionic polarization inside the perovskite has a negligible contribution to exciton formation. The spectra also efficiently uncovered the effective mass of electron-hole pairs. Our spectroscopic method and the results profoundly enrich the understanding of the photophysics in perovskite materials for photovoltaic applications.