Human occupants themselves constitute an important source of volatile organic compounds (VOCs) in indoor environments through breath and dermal emissions. In order to quantify VOC emissions from occupants under real-world settings, previous indoor observational studies often determined emission factors (i.e., average emission rates per person). However, the values obtained across these studies exhibited large variability, and the causes of this variability still need to be understood. Herein we report 10-day real-time VOC measurements in a university student office, using a proton transfer reaction-quadrupole interface-time-of-flight mass spectrometer. A method was developed to identify VOCs of primary human origin and to quantify the corresponding emission factors, accounting for the dynamically changing occupancy level and ventilation rate in the assessed office. We found that the emission factors of many dermally emitted VOCs strongly increased as the ozone concentration increased from <3 to 10–15 ppb. These VOCs include geranyl acetone, 6-methyl-5-hepten-2-one (6-MHO), and C10-C12 saturated aldehydes, which align with characteristic first-generation ozonolysis products of skin oil. The strongest increase occurred for 6-MHO, from 113 to 337 μg/h/p. In comparison, acetone and isoprene, which are primarily emitted from human breath, varied little with the ozone level. In light of this finding, we conducted an integrated analysis of emission factors reported in the literature for two frequently reported species, namely, 6-MHO and decanal. Ozone concentration alone can explain 94–97% of the variation in their emission factors across previous studies, and the best-estimated ozone dependence obtained using the literature data is consistent with those obtained in the current study. These results suggest that the ozone concentration is a key factor regulating emission factors of many dermally emitted VOCs in real indoor environments, which has to be considered when reporting or using the emission factors.
Quorum sensing (QS)-based manipulations emerge as a promising solution for biofilm reactors to overcome challenges from inefficient biofilm formation and lengthy start-ups. However, the ecological mechanisms underlying how QS regulates microbial behaviors and community assembly remain elusive. Herein, by introducing different levels of N-acyl-homoserine lactones, we manipulated the strength of QS during the start-up of moving bed biofilm reactors and compared the dynamics of bacterial communities. We found that enhanced QS elevated the fitness of fast-growing bacteria with high ribosomal RNA operon (rrn) copy numbers in their genomes in both the sludge and biofilm communities. This led to notably increased extracellular substance production, as evidenced by strong positive correlations between community-level rrn copy numbers and extracellular proteins and polysaccharides (Pearson's r = 0.529−0.830, P < 0.001). Network analyses demonstrated that enhanced QS significantly promoted the ecological interactions among taxa, particularly cooperative interactions. Bacterial taxa with higher network degrees were more strongly correlated with extracellular substances, suggesting their crucial roles as public goods in regulating bacterial interactions and shaping network structures. However, the assembly of more cooperative communities in QS-enhanced reactors came at the cost of decreased network stability and modularity. Null model and dissimilarity-overlap curve analysis revealed that enhanced QS strengthened stochastic processes in community assembly and rendered the universal population dynamics more convergent. Additionally, these shaping effects were consistent for both the sludge and biofilm communities, underpinning the planktonic-to-biofilm transition. This work highlights that QS manipulations efficiently drive community assembly and confer specialized functional traits to communities by recruiting taxa with specific life strategies and regulating interspecific interactions. These ecological insights deepen our understanding of the rules governing microbial societies and provide guidance for managing engineering ecosystems.
The speedy raise of residential buildings' carbon emissions is a hindrance to achieving China's 2030 carbon peak goal. This study constructs an assessment framework for comprehensive consideration of 30 Chinese provinces' socioeconomic circumstances, energy demand, and emissions reduction technology to meet the consistent coupling degree of equity and efficiency (CDEE). This study is the first to propose an allocation scheme for equilibrating provincial carbon increments for rural and urban residential buildings in 2030 under carbon peaking constraints. The relevant results are fourfold. (1) Residential building's floor area per capita and energy carbon emissions coefficients are the soliddest drivers to facilitate and inhibit the raise of carbon emissions during 2010–2020. (2) Through dynamic Monte Carlo simulation from 2021 to 2030, we demonstrate that provinces with the most gamey carbon emissions in urban and rural areas include Shandong, at 121.52 (± 5.50) Mt. and Hebei, at 61.34 (± 3.08) Mt. in 2030, respectively. (3) A CDEE of 52.3% (biased equity) in urban areas and 34.5% (biased efficiency) in rural areas indicates equilibrated allocation of provincial carbon increment. (4) In the final 2030 allocation scheme, the greatest carbon mitigation pressures are in Beijing (11.34 Mt) and Heilongjiang (3.23 Mt), and the provinces with the largest carbon increment in urban areas include Hebei, Henan, and Guangdong, while the largest carbon increments in rural areas are in Hebei, Henan, and Guangdong. Overall, this study furnishes a targeted and valuable decision making reference for the government to determine provincial carbon peak goals for Chinese residential buildings.
Chlorinated paraffins (CPs), mainly short-chain CPs (SCCPs) and medium-chain CPs (MCCPs), are currently the most produced and used industrial chemicals related to persistent organic pollutants (POPs) globally. These chemicals are widely detected in the environment and in the human body. As the release of SCCPs and MCCPs from products represents only a small fraction of their stock in products, the potential long-term release of CPs from a large variety of products at the waste stage has become an issue of great concern. The results of this study showed that, by 2050, SCCPs and MCCPs used between 2000 and 2021 will cumulatively generate 226.49 Mt of CP-containing wastes, comprising 8610.13 kt of SCCPs and MCCPs. Approximately 79.72 Mt of CP-containing wastes is predicted to be generated abroad through the international trade of products using SCCPs and MCCPs. The magnitude, distribution, and growth of CP-containing wastes subject to environmentally sound disposal will depend largely on the relevant provisions of the Stockholm and Basel Conventions and the forthcoming global plastic treaty. According to multiple scenarios synthesizing the provisions of the three conventions, 26.6–101.1 Mt of CP-containing wastes will be subject to environmentally sound disposal as POP wastes, which would pose a great challenge to the waste disposal capacity of China, as well as for countries importing CP-containing products. The additional 5-year exemption period for MCCPs is expected to see an additional 10 Mt of CP-containing wastes subject to environmentally sound disposal. Thus, there is an urgent need to strengthen the Stockholm and Basel Conventions and the global plastic treaty.
This paper aims to examine the impact of the digital economy on urban entrepreneurship and its spatial spillover effects. To achieve this purpose, this research relies on data from 252 prefecture-level cities in China from 2012 to 2019. The findings demonstrate that the development of the digital economy has a positive influence on entrepreneurial activity in cities, with particularly effects observed robust at higher quantile levels. Additionally, the results suggest that urban entrepreneurial activity may be a siphoning effect, impeding entrepreneurship in neighboring cities. Furthermore, further investigation shows regional and policy heterogeneity.
Promoting rural family entrepreneurship is an effective way to realize rural revitalization. The primary aim of this study is to assess the entrepreneurial impact of family social capital on rural households in China. The objective of this study is to understand how family social capital affects rural entrepreneurship in a Chinese context. Using data from the 2020 China Family Panel Studies, this study empirically tests the effect of family social capital on rural family entrepreneurship. Research shows that family social capital is significantly and positively correlated with rural family entrepreneurship, indicating that it is an essential determinant in promoting rural family entrepreneurship. Internet use is an effective transmission path for family social capital, which affects rural entrepreneurship, and the impact of rural entrepreneurship varies with family size and household head characteristics. This study not only enriches the theoretical understanding of rural entrepreneurship but also sheds light on the behavioral mechanisms that explain the entrepreneurial process of rural households. To promote rural entrepreneurship and revitalization, it is important to be adept at activating family social capital.
Injecting CO2 when the gas reservoir of tight sandstone is depleted can achieve the dual purposes of greenhouse gas storage and enhanced gas recovery (CS-EGR). To evaluate the feasibility of CO2 injection to enhance gas recovery and understand the production mechanism, a numerical simulation model of CS-EGR in multi-stage fracturing horizontal wells is established. The behavior of gas production and CO2 sequestration is then analyzed through numerical simulation, and the impact of fracture parameters on production performance is examined. Simulation results show that the production rate increases significantly and a large amount of CO2 is stored in the reservoir, proving the technical potential. However, hydraulic fractures accelerate CO2 breakthrough, resulting in lower gas recovery and lower CO2 storage than in gas reservoirs without fracturing. Increasing the length of hydraulic fractures can significantly increase CH4 production, but CO2 breakthrough will advance. Staggered and spaced perforation of hydraulic fractures in injection wells and production wells changes the fluid flow path, which can delay CO2 breakthrough and benefit production efficiency. The fracture network of massive hydraulic fracturing has a positive effect on the CS-EGR. As a result, CH4 production, gas recovery, and CO2 storage increase with the increase in stimulated reservoir volume.
In economics and many other forecasting domains, the real world problems are too complex for a single model that assumes a specific data generation process. The forecasting performance of different methods changesChange(s) depending on the nature of the time series. When forecasting large collections of time series, two lines of approaches have been developed using time series features, namely feature-based model selection and feature-based model combination. This chapter discusses the state-of-the-art feature-based methods, with reference to open-source software implementationsImplementation.
Long and skinny molecular filaments running along Galactic spiral arms are known as “bones,” since they make up the skeleton of the Milky Way. However, their origin is still an open question. Here, we compare spectral images of HI taken by the Five-hundred-meter Aperture Spherical radio Telescope (FAST) with archival CO and Herschel dust emission to investigate the conversion from HI to H2 in two typical Galactic bones, CFG028.68-0.28 and CFG047.06+0.26. Sensitive FAST HI images and an improved methodology enabled us to extract HI narrow self-absorption (HINSA) features associated with CO line emission on and off the filaments, revealing the ubiquity of HINSA toward distant clouds for the first time. The derived cold HI abundances, [HI]/[H2], of the two bones range from ∼(0.5 to 44.7) × 10−3, which reveal different degrees of HI–H2 conversion, and are similar to those of nearby, low-mass star-forming clouds, Planck Galactic cold clumps, and a nearby active high-mass star-forming region G176.51+00.20. The HI–H2 conversion has been ongoing for 2.2–13.2 Myr in the bones, a timescale comparable to that of massive star formation therein. Therefore, we are witnessing young giant molecular clouds (GMCs) with rapid massive star formation. Our study paves the way of using HINSA to study cloud formation in Galactic bones and, more generally, in distant GMCs in the FAST era.
Liquid loading presents a formidable challenge for mature gas wells, often resulting in substantial economic losses. Traditional research has predominantly centered on the analysis of gas-liquid two-phase flow within the wellbore to predict critical gas velocity or rate, aiding in identifying the onset of liquid loading. This study introduces a fully coupled compositional wellbore-reservoir simulator designed to detect liquid loading in both vertical and inclined gas wells. Leveraging the drift-flux model to evaluate flow pattern transitions, this simulator employs pressure or rate constraints at the wellhead as boundary conditions. It comprehensively captures the flow dynamics in both the wellbore and reservoir, unveiling significant changes in gas production rate, water production rate, gas velocity, flow regime, and the reserved position of the liquid film under liquid-loaded conditions. Moreover, the accumulation of liquid at the bottom hole leads to increased reservoir pressure and gas saturation near the wellbore. The simulator predicts a typical unstable production period, emphasizing its crucial role in implementing effective strategies to mitigate liquid loading. This paper investigates the capability of the coupled wellbore-reservoir model to characterize transient liquid loading phenomena from a systematic perspective. The proposed model can function as a real-time tool for predicting the status of liquid loading in gas wells.