The occurrence of polycyclic aromatic hydrocarbons (PAHs) and nitrated derivatives (NPAHs), as well as their transformation may have significant health impacts on humans. To investigate the level, spatial distribution and the transformation process of PAHs and NPAHs in North China, we performed a gridded field passive air sampling campaign in summer of 2011. The median concentration of 25 PAH congeners and 13 NPAHs was 294 ng m−3 (or 26.7 μg sample−1) and 203 ng sample−1, respectively. Relative higher level of PAHs in Shanxi Province and NPAHs in megacities was observed. In North China, coal/biomass combustion and photochemical formation was the predominant source of PAHs and NPAHs, respectively. To investigate the relationship between these pollutants, a model incorporating NPAHs, PAHs and NO2 was established, and the result indicated that NO2 will promote the transformation processes from PAHs to NPAHs, which may increase the total toxicity of PAH–NPAH mixtures.
The occurrence of polycyclic aromatic hydrocarbons (PAHs) and nitrated derivatives (NPAHs), as well as their transformation may have significant health impacts on humans. To investigate the level, spatial distribution and the transformation process of PAHs and NPAHs in North China, we performed a gridded field passive air sampling campaign in summer of 2011. The median concentration of 25 PAH congeners and 13 NPAHs was 294 ng m(-3) (or 26.7 mu g sample(-1)) and 203 ng sample(-1), respectively. Relative higher level of PAHs in Shanxi Province and NPAHs in megacities was observed. In North China, coal/biomass combustion and photochemical formation was the predominant source of PAHs and NPAHs, respectively. To investigate the relationship between these pollutants, a model incorporating NPAHs, PAHs and NO2 was established, and the result indicated that NO2 will promote the transformation processes from PAHs to NPAHs, which may increase the total toxicity of PAH-NPAH mixtures. (C) 2014 Elsevier Ltd. All rights reserved.
In a magnetic cusp gun, the canonical-angular-momentum (CAM) spread of the initially emitted electrons is crucial in generating substantial beam velocity spread. A new method called electron beam flow-feature compensation is proposed to build an axis-encircling electron beam with zero velocity spread by optimizing the cross-flow trajectories to compensate for the initial CAM spread. This method provides an effective solution to the velocity-spread problem in terahertz gyrotrons and increases the emission current to a level that is several times higher than the level that can be obtained using current technology.
Recently, inverted planar heterojunction (PHJ) perovskite solar cells have been developed rapidly by numerous preparations and relative optimizations. Sequential solution deposition is easy to manipulate but it is difficult to control the thickness and morphology of perovskite films. In this article, we report an improved sequential deposition, named twice dipping-vapor solution deposition (TD-VSD) technology, to accurately achieve superior perovskite films. It is demonstrated that the morphology of perovskite films depended on the substrate temperatures as well as the dipping times. The resulting solar cells showed the power conversion efficiency as high as 11.77% based on the ideal thickness and morphology. This work provides a simple but effective fabrication to well control the perovskite films and enhance the power conversion efficiency for inverted PHJ solar cells.
3,4,9,10-Tetracyano- and tetrachlorocoronene-1,6,7,12-tetracarboxy diimides with low LUMO levels at -3.9 to -4.2 eV are developed. These molecules manifest potent n-type semiconductive capability in solution-processed field-effect transistors, with electron mobilities of up to 0.16 cm(2) V-1 s(-1) measured in air. The device performances of analogous molecules elucidate the importance of side chain structures in the semiconductive properties.
Indeno[1,2-b]fluorene derivatives with trimethlysilylethynyl substituents at the 6- and 12-positions were found to undergo cyclo-dimeerzatin cyclo-trimaerzatio and higher oligomerization at room tempeatrue. The cyclic dimer feature a novel double-decker motif, composed of two face-to-face stacked bis(propadienylide)dihydroindeno[1,2-b] flourenes with a short centroid-to- centroid distance of 3.50 angstrom. The existence of a cyclic timer and higher oligemers was indeno[1,2-b]fluorene moiety.
We examine the role of demographics and family/social interaction in Chinese household finance. The impacts of demographic characteristics are not limited to stock market participation, but extend to other financial activities. Households with strong family and social interaction are more likely to save, invest in risky assets and borrow. Family interaction is positively related to informal financing.
We construct a density functional theory for two-dimensional electron (hole) gases subjected to both strong magnetic fields and external potentials. In particular, we are focused on regimes near even-denominator filling factors, in which the systems form composite fermion liquids. Our theory provides a systematic and rigorous approach to determine the properties of ground states in a fractional quantum Hall regime that is modified by artificial structures. We also propose a practical way to construct an approximated functional.
The popularity of stereo images and various display devices poses the need of stereo image retargeting techniques. Existing warping-based retargeting methods can well preserve the shape of salient objects in a retargeted stereo image pair. Nevertheless, these methods often incur depth distortion, since they attempt to preserve depth by maintaining the disparity of a set of sparse correspondences, rather than directly controlling the warping. In this paper, by considering how to directly control the warping functions, we propose a warping-based stereo image retargeting approach that can simultaneously preserve the shape of salient objects and the depth of 3D scenes. We first characterize the depth distortion in terms of warping functions to investigate the impact of a warping function on depth distortion. Based on the depth distortion model, we then exploit binocular visual characteristics of stereo images to derive region-based depth-preserving constraints which directly control the warping functions so as to faithfully preserve the depth of 3D scenes. Third, with the region-based depth-preserving constraints, we present a novel warping-based stereo image retargeting framework. Since the depth-preserving constraints are derived regardless of shape preservation, we relax the depth-preserving constraints to fulfill a tradeoff between shape preservation and depth preservation. Finally, we propose a quad-based implementation of the proposed framework. The results demonstrate the efficacy of our method in both depth and shape preservation for stereo image retargeting.