Calcium phosphate is widely used for the remediation of lead-contaminated sites, where calcium/lead phosphate coprecipitates (Ca/Pb CoPs) form. This research investigated such coprecipitation with model low-molecular-weight organics (LMWOs), produced in the rhizosphere with representative functional groups, which were found to regulate both the composition (Ca/Pb and C/Pb ratios) and stability (aggregation and transformation) of Ca/Pb CoPs. The strong complexation ability of –SH in l-cysteine with aqueous Ca2+/Pb2+ ions inhibited coprecipitation to a great extent. Meanwhile, coprecipitates with lysine containing both –NH2 and –COOH had a higher Ca/Pb ratio than those with citrate containing only –COOH, probably due to the elevated local supersaturation caused by both –NH2 and –COOH in lysine that attracted phosphate ions and cations, promoting Ca doping in CoPs. Also, the strong binding of both –NH2 and –COOH with coprecipitates resulted in a higher C/Pb ratio for the CoPs with lysine than citrate. The oriented aggregation of nano-CoPs formed needle-shaped hydroxylpyromorphite crystals without organics. Unexpectedly, lysine/citrate disrupted and l-cysteine promoted such oriented aggregation, resulting in inhibited and promoted crystallinity, respectively. This study provided new mechanistic insights on LMWO effects on Ca/Pb CoP formation and their stability and can help understand Pb speciation and availability in the rhizosphere.
Integration between electronics and biology is often facilitated by iontronics, where ion migration in aqueous media governs sensing and memory. However, the Debye screening effect limits electric fields to the Debye length, the distance over which mobile ions screen electrostatic interactions, necessitating external voltages that constrain the operation speed and device design. Here we report a high-speed in-memory sensor based on vanadium dioxide (VO2) that operates without an external voltage by leveraging built-in electric fields within the Debye length. When VO2 contacts a low-work-function metal (for example, indium) in a salt solution, electrochemical reactions generate indium ions that migrate into the VO2 surface under the native electric field, inducing a surface insulator-to-metal phase transition of VO2. The VO2 conductance increase rate reflects the salt concentration, enabling in-memory sensing, or memsensing of the solution. The memsensor mimics Caenorhabditis elegans chemosensory plasticity to guide a miniature boat for adaptive chemotaxis, illustrating low-power aquatic neurorobotics with fewer memory units.
Beryllium isotopes (stable 9Be and cosmogenic meteoric 10Be) enter the oceans through distinct pathways – i.e., from the continents and the atmosphere respectively – and display non-conservative behaviour in seawater. This isotope system has served as a powerful tool for quantifying a variety of processes, including geomagnetism, sedimentation, continental input, and ocean circulation. However, processes at land–ocean boundaries and within the ocean interior may either amplify or buffer the seawater isotope response to environmental changes. In the last decade, substantial effort has been invested in understanding external sources and internal cycling of Be isotopes, offering an excellent opportunity to revisit their modern oceanic cycle. Here, we investigate the controls on the modern oceanic cycling of Be isotopes using a three-dimensional ocean model, constrained by observational data on input fluxes and water-column distributions of 9Be and 10Be. In addition to modelling the previously known controls, we highlight the key role of marine benthic fluxes and scavenging onto particulate organic matter and opal in determining the mass balance and spatial distribution of Be isotopes. Inter-basin Be transport by the circulation is less important than external inputs at continent/atmosphere–ocean boundaries, except in the South Pacific. Therefore, the distribution of seawater 10Be/9Be ratios largely reflects that of the external inputs in most basins in the modern ocean. Finally, we apply our data-constrained mechanistic model to test the sensitivity of basin-wide 10Be/9Be ratios to changes of external sources and internal cycling. This analysis shows that seawater 10Be/9Be ratios are to some extent buffered against changes in continental denudation. For example, a 50 % decrease in denudation rates results in a 13–48 % increase in ocean-wide 10Be/9Be ratios. Moreover, the interplay between particle scavenging and ocean circulation can cause divergent responses in 10Be/9Be ratios in different basins. Weaker scavenging (e.g., 50 % decrease in intensity) would increase the homogenising effect of ocean circulation, making North Atlantic and North Pacific 10Be/9Be ratios converge (∼20 % change in isotope ratios). The mechanistic understanding developed from this Be cycling model provides important insights into the various applications of marine Be isotopes, and offers additional tools to assess the causes of spatio-temporal Be isotope variations. We also identify the key oceanic processes that require further constraints to achieve a complete understanding of Be cycling in the modern ocean and back through time.
Using the census data from 2000-2015 and a pseudo-event study design, we estimate the motherhood penalty in China and explore its association with declining fertility. We find that one-third of working women leave their jobs in the year when they give birth, and the penalty persists for over eight years. The motherhood penalty increases significantly across almost all provinces during this period, and provinces with larger increases in the penalty experience greater declines in fertility rates. Using a mover-based design, we find that the rising motherhood penalty has caused a significant decline in the total fertility rate.
Existing methods for moving sound source localization and tracking face significant challenges when dealing withan unknown number of sound sources, which substantially limits their practical applications. This paper proposes amoving sound source tracking method based on source signal envelopes that does not require prior knowledge ofthe number of sources. First, an encoder-decoder attractor (EDA) method is used to estimate the number of sourcesand obtain an attractor for each source, based on which the signal envelope of each source is estimated. This signalenvelope is then used as a clue for tracking the target source. The proposed method has been validated throughsimulation experiments. Experimental results demonstrate that the proposed method can accurately estimate thenumber of sources and precisely track each source.
Multi-focus image fusion (MFIF) is a critical technique for enhancing depth of field in photography, producing an all-in-focus image from multiple images captured at different focal lengths. While deep learning has shown promise in MFIF, most existing methods ignore the physical model of defocus blurring in their neural architecture design, limiting their interoperability and generalization. This paper presents a novel framework that integrates explicit defocus blur modeling into the MFIF process, leading to enhanced interpretability and performance. Leveraging an atom-based spatially-varying parameterized defocus blurring model, our approach first calculates pixel-wise defocus descriptors and initial focused images from multi-focus source images through a scale-recurrent fashion, based on which soft decision maps are estimated. Afterward, image fusion is performed using masks constructed from the decision maps, with a separate treatment on pixels that are probably defocused in all source images or near boundaries of defocused/focused regions. Model training is done with a fusion loss and a cross-scale defocus estimation loss. Extensive experiments on benchmark datasets have demonstrated the effectiveness of our approach.