Flowering phenology of plants, which is important for reproductive growth, has been shown to be influenced by climate change. Understanding how flowering phenology responds to climate change and exploring the variation of this response across plant groups can help predict structural and functional changes in plant communities in response to ongoing climate change. Here, we used long-term collections of 33 flowering plant species from the Gongga Mountains (Mt. Gongga hereafter), a biodiversity hotspot, to investigate how plant flowering phenology changed over the past 70 years in response to climate change. We found that mean flowering times in Mt. Gongga were delayed in all vegetation types and elevations over the last 70 years. Furthermore, flowering time was delayed more in lowlands than at high elevations. Interestingly, we observed that spring-flowering plants show earlier flowering times whereas summer/autumn plants show delayed flowering times. Non-synchronous flowering phenology across species was mainly driven by changes in temperature and precipitation. We also found that the flowering phenology of 78.8% plant species was delayed in response to warming temperatures. Our findings also indicate that the magnitude and direction of variation in plant flowering times vary significantly among species along elevation gradients. Shifts in flowering time might cause trophic mismatches with co-occurring and related species, affecting both forest ecosystem structure and function.
One of the most important mechanism design policies in college admissions is to let students choose a college major sequentially (college-then-major choice) or jointly (college-major choice). In the context of the Chinese meta-major reforms that transition from college-major choice to college-then-major choice, we provide the first experimental evidence on the information frictions and heterogeneous preferences that students have in their response to the meta-major option. In a randomized experiment with a nationwide sample of 11,424 high school graduates, we find that providing information on the benefits of a meta-major significantly increased students’ willingness to choose the meta-major; however, information about specific majors and assignment mechanisms did not affect students major choice preferences. We also find that information provision mostly affected the preferences of students who were from disadvantaged backgrounds, lacked accurate information, did not have clear major preferences, or were risk loving.
The commercialization of academic patents is a basic means for universities to promote economic growth and upgrade the industrial innovation of enterprises. However, among developing countries, the commercialization rate of university patents is generally low. This study utilizes data from 65 universities which are directly under the Ministry of Education of China to analyze the influencing factors and mechanisms of academic patent commercialization. The findings show that the proportion of associate professors, the size of service staff transforming research and development achievement, and the proportion of basic research funding in universities are positively correlated with the commercialization rate of university patents. In addition, these factors indirectly affect the commercialization of university patents by affecting neighboring universities; that is, there are spatial spillover effects in the commercialization of university patents between neighboring universities. These empirical results indicate that universities can promote the commercialization of university patents by optimizing the structure of faculty, developing the R&D achievement transformation service staff team, and strengthening investment in basic research.
Because of land privatisation and marketisation in rural areas, community-based adaptation to climate change may face new challenges. A field survey conducted on the Qinghai–Tibetan Plateau (QTP) shows that herders with a grassland collective management system (CMS) suffer higher livestock mortality than those with an individual management system (IMS) during the same extreme climatic events, in contrast to previous research findings. This study seeks to explain this contrast. The results show that although local herders have begun to rely on market-related adaptation strategies to cope with climate change, IMS herders are more inclined to rent-in grassland, while CMS herders are more inclined to purchase fodder. The high-cost grassland renting-in strategy reduces livestock mortality and total household economic loss more effectively than purchasing fodder during snow disasters. An important reason for this is that IMS strengthens market concepts and promotes interaction between herders and external markets, especially the grassland rental market, while CMS continues past grazing traditions and maintains traditional social relationships and collective concepts within the community. CMS herders fail to rent-in grassland due to psychological free-riding incentives and scale mismatch. In the face of repeated climatic disasters, however, CMS herders have also begun to overcome various obstacles to entering the grassland rental market through self-organization and are gradually forming a new pathway of adaptation to climate change.
The poor colloidal stability of magnetite nanoparticles (MNPs) limits their mobility and application, so various organic coatings (OCs) were applied to MNPs. Here, a comparative study on the colloidal stability of MNPs coated with acetic (HAc) and polyacrylic acids (PAA) was conducted under varied pH (5.0–9.0) in the presence of different concentrations of cations and anions, as well as humic acid (HA). Comparing the effects of various cations and anions, the stability of both HAc/PAA-MNPs followed the order: Na+ > Ca2+and PO43− > SO42− > Cl−, which could be explained by their adsorption behaviors onto HAc/PAA-MNPs and the resulting surface charge changes. Under all conditions even with more anion adsorption onto HAc-MNPs (0.14–22.56 mg/g) than onto PAA-MNPs (0.04–18.34 mg/g), PAA-MNPs were more negatively charged than HAc-MNPs, as PAA has a lower pHIEP (2.6 ± 0.1) than that of HAc (3.7 ± 0.1). Neither the HAc nor PAA coatings were displaced by phosphate even at considerably high phosphate concentration. Compared with HAc-MNPs, the stability of PAA-MNPs was greatly improved under all studied conditions, which could be due to both stronger electrostatic and additional steric repulsion forces among PAA-MNPs. Besides, under all conditions, Derjaguin-Landau-Verwey-Overbeek (DLVO) explained well the aggregation kinetic of HAc-MNPs; while extended DLVO (EDLVO) successfully predict that of PAA-MNPs, indicating steric forces among PAA-MNPs. The aggregation of HAc/PAA-MNPs was all inhibited in varied electrolyte solutions by HA (2 mg C/L) addition. This study suggested that carboxyl coatings with higher molecular weights and pKa values could stabilize MNPs better due to stronger electrostatic and additional steric repulsion. However, in the presence of HA, these two forces were mainly controlled by adsorbed HA instead of the organic pre-coatings on MNPs.
A compilation of new advances made in the research field of laboratory reaction kinetics in China's Key Development Project for Air Pollution Formation Mechanism and Control Technologies was presented. These advances are grouped into six broad, interrelated categories, including volatile organic compound (VOC) oxidation, secondary organic aerosol (SOA) formation, new particle formation (NPF) and gas-particle partitioning, ozone chemistry, model parameters, and secondary inorganic aerosol (SIA) formation, highlighting the laboratory work done by Chinese researchers. For smog chamber applications, the current knowledge gained from laboratory studies is reviewed, with emphasis on summarizing the oxidation mechanisms of long-chain alkanes, aromatics, alkenes, aldehydes/ketones in the atmosphere, SOA formation from anthropogenic emission sources, and oxidation of aromatics, isoprene, and limonene, as well as SIA formation. For flow tube applications, atmospheric oxidation mechanisms of toluene and methacrolein, SOA formation from limonene oxidation by ozone, gas-particle partitioning of peroxides, and sulfuric acid-water (H2SO4-H2O) binary nucleation, methanesulfonic acid-water (MSA-H2O) binary nucleation, and sulfuric acid-ammonia-water (H2SO4-NH3-H2O) ternary nucleation are discussed.
In-situ catalytic deNOx is a promising NOx control technology for circulating fluidized bed (CFB) boilers. In this application, matching the conditions between the catalyst and gaseous species is crucial. To understand this, a comprehensive computational particle fluid dynamics (CPFD) model was established; flow, combustion, and NOx emission characteristics in an industrial CFB boiler were elaborated; 20 catalysts with various sizes and densities were designed, and their degree of matching with the gaseous species was evaluated. The simulation results indicated that NOx was gradually produced at the bottom of the furnace and attained its maximum concentration at the elevation of secondary air; CO showed a high concentration in the bottom dense-phase zone; and the homogeneous NO-CO reaction is too weak to effectively reduce NOx. With catalyst application, the NO-CO reaction was evidently enhanced and the in-furnace NOx concentration decreased significantly. The 20 evaluated catalysts can be categorized as dipleg deposition, fluidization circulating, furnace suspension, and furnace deposition types. While the last three types of catalysts could match the spatial and temporal distribution of CO and NOx species well, the furnace suspension-type catalyst produced an optimal matching degree and maximum deNOx efficiency.
Unexpected health shocks may bring catastrophic consequences for households. This paper examines the effect of unexpected adverse health shocks on household members' physical and mental health, labor supply, household income and asset, and health behaviors in China by analyzing two nationally representative datasets and adopting a difference-in-differences method augmented with coarsened exact matching. We find that an unexpected health shock results in a discounted out-of-pocket medical expenditure of 16,943 RMB (US$ 2647) over five years for an average household, a reduction of household income per capita of 841 RMB per year (US$ 131, or 6.0% of household annual income per capita), and a loss of net household asset per capita of 13,635 RMB (US$ 2130, or 9.7% of household asset per capita). It raises the probability of an average household applying for public poverty relief allowance by 2.8 percentage points. In addition, we document a strong intra-household spillover effect of health shocks on mental health and health behaviors. A simple back-of-envelope calculation shows that the health shock induces a private cost of 34,966 RMB (US$ 5463) over 5 years for an average household, and incurs a social financial burden of 6066 RMB (US$ 948) in 5 years per household in medical reimbursement and social welfare transfers. At a national scale, the total social burden of health shocks from cardiovascular and cerebrovascular diseases amounts to 1.1 trillion RMB (US$ 172.1 billion) over 5 years.
Achieving efficient degradation of organic pollutants via activation of sulfite is meaningful but challenging. Herein, we have constructed a heterogeneous catalyst system involving Co3O4 and TiO2 nanoparticles to form the p-n heterojunction (Co3O4/TiO2) to degrade acetaminophen (ACE) through photocatalytic activation of sulfite. Specifically, X-ray photoelectron spectroscopy analysis and theoretical calculations provide compelling evidence of electron transfer from Co3O4 to TiO2 at the heterointerface. The interfacial electron redistribution of Co3O4/TiO2 tunes the adsorption energy of HSO3‒/SO32‒ in sulfite activation process for enhanced the catalytic activity. Owing to its unique heterointerface, the degradation efficiency of ACE reached 96.78% within 10 min. The predominant active radicals were identified as •OH, h+, and SOx•− through radical quenching experiments and electron spin resonance capture. Besides, the possible degradation pathway was deduced by monitoring the generated intermediate products. Thereafter, the enhanced roles of well-engineered compositing interface in photocatalytic activation of sulfite for complete degradation of ACE were unveiled that it can improve light absorption ability, facilitate the generation of active species, and optimize reactive pathways. Considering that sulfite is a waste from flue gas desulfurization process, the photocatalytic activation of sulfite system will open up new avenues of beneficial use of air pollutants for the removal of pharmaceutical wastewater.
Implementing the Kigali Amendment to the Montreal Protocol has imposed certain restrictions on the production and consumption of hydrofluorocarbons (HFCs). Taking this opportunity to promote the alternatives of high global warming potential (GWP) HFC refrigerants in the room air conditioner (RAC) sector as well as improve the energy efficiency can bring double benefits. With the RAC sector as an example, a demand-emissions-cost model is developed to assess the potential and costs of emission reductions in different regions of China under different scenarios. The model includes three scenarios: a business as usual (BAU) scenario, a Kigali energy efficiency (KAE) scenario with simultaneous energy efficiency improvements following the Kigali amendment, and an accelerated transition energy efficiency (ATE) scenario with accelerated HFCs reduction and energy efficiency improvements. The results show that under the KAE and ATE scenario, the GHG emissions of the RAC sector will peak in 2025 at 389.8–393.9 Mt CO2-eq and 378.8–382.8 Mt CO2-eq in China. The main contribution to this result is the alternative of low GWP refrigerants. From 2021 to 2060, the cumulative direct emission reductions are about 6.4–7.4 Gt CO2-eq and 8.5–9.5 Gt CO2-eq in KAE and ATE, and the cumulative indirect emission re- ductions for both scenarios are 1.6–1.8 Gt CO2-eq. The cumulative abatement costs are $286–321 billion and $288–322 billion (prices in 2020). Under the ATE scenario, direct emissions from refrigerants in the RAC sector are near zero in 2060, and indirect emissions depend on the power system structure. The RAC sector’s average abatement cost varies significantly in diverse climatic environments. Given the variation in average abatement cost, it is critical to tailor mitigation policies to local conditions to ensure maximum benefits.
The nanoconfinement effect in Fenton-like reactions shows great potential in environmental remediation, but the construction of confinement structure and the corresponding mechanism are rarely elucidated systematically. Herein, we proposed a novel peroxymonosulfate (PMS) activation system employing the single Fe atom supported on mesoporous N-doped carbon (FeSA-MNC, specific surface area = 1520.9 m2/g), which could accelerate the catalytic oxidation process via the surface-confinement effect. The degradation activity of the confined system was remarkably increased by 34.6 times compared to its analogue unconfined system. The generation of almost 100% high-valent iron-oxo species was identified via 18O isotope-labeled experiments, quenching tests, and probe methods. The density functional theory illustrated that the surface-confinement effect narrows the gap between the d-band center and Fermi level of the single Fe atom, which strengthens the charge transfer rate at the reaction interface and reduces the free energy barrier for PMS activation. The surface-confinement system exhibited excellent pollutant degradation efficiency, robust resistance to coexisting matter, and adaptation of a wide pH range (3.0–11.0) and various temperature environments (5–40 °C). Finally, the FeSA-MNC/PMS system could achieve 100% sulfamethoxazole removal without significant performance decline after 10,000-bed volumes. This work provides novel and significant insights into the surface-confinement effect in Fenton-like chemistry and guides the design of superior oxidation systems for environmental remediation.
Solar-driven photosynthesis is a sustainable process for the production of hydrogen peroxide, the efficiency of which is plagued by side reactions. Metal-free covalent organic frameworks (COFs) that can form suitable intermediates and inhibit side reactions show great promise to photo-synthesize H2O2. However, the insufficient formation and separation/transfer of photogenerated charges in such materials restricts the efficiency of H2O2 production. Herein, we provide a strategy for the design of donor-acceptor COFs to greatly boost H2O2 photosynthesis. We demonstrate that the optimal intramolecular polarity of COFs, achieved by using suitable amounts of phenyl groups as electron donors, can maximize the free charge generation, which leads to high H2O2 yield rates (605 μmol g−1 h−1) from water, oxygen and visible light without sacrificial agents. Combining in-situ characterization with computational calculations, we describe how the triazine N-sites with optimal N 2p states play a crucial role in H2O activation and selective oxidation into H2O2. We further experimentally demonstrate that H2O2 can be efficiently produced in tap, river or sea water with natural sunlight and air for water decontamination.
The ultra-low NOx emission requirement (50 mg/m3) brings great challenge to CFB boilers in China. To further tap the NOx abatement potential, full understanding the fundamentals behind CFB boilers is needed. To achieve this, a comprehensive CPFD model is established and verified; gas-solid flow, combustion, and NOx emission behavior in an industrial CFB boiler are elaborated; influences of primary air volume and coal particle size on furnace performance are evaluated. Simulation results indicate that there exists a typical core-annular flow structure in the boiler furnace. Furnace temperature is highest in the bottom dense-phase zone (about 950 °C) and decreases gradually along the furnace height. Oxygen-deficient combustion results in high CO concentration and strong reducing atmosphere in the lower furnace. NOx concentration gradually increases in the bottom furnace, reaches maximum at the elevation of secondary air inlet, and then decreases slightly in the upper furnace. Appropriate decreasing the primary air volume and coal particle size would increase the CO concentration and intensify the in-furnace reducing atmosphere, which favors for NOx reduction and low NOx emission from CFB boilers.
