Triangular-shaped molecular random tiling and molecular rotation in two-dimensional glassy networks

摘要:

Macrocycle-1 molecules can self-assemble into glassy state networks via van der Waals force and form many triangular nanopores in networks. The nanopores can be expressed by triangular tilings, which lead to a particularly rich range of arrangements. Moreover an interesting molecular rotation phenomenon was observed in the glassy networks.

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