Citation:
Zhao, D. ; Moore, J. S. *. Nucleation-Elongation: A Mechanism for Cooperative Supramolecular Polymerization. Org. Biomol. Chem. 2003, 1, 3471-3491.
摘要:
The kinetic and thermodynamic characteristics of polymerizations following a cooperative, nucleation-elongation mechanism are discussed in comparison to those of non-cooperative, isodesmic polymerizations. Nucleation-elongation polymerization is a relatively unexplored avenue of synthetic polymer chemistry and offers some unique and interesting thermodynamic and kinetic attributes not found in the more classical mechanisms of polymer chemistry.See also: 2003