<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Zhu, Junli</style></author><author><style face="normal" font="default" size="100%">Dai, Cancan</style></author><author><style face="normal" font="default" size="100%">Ma, Mengyue</style></author><author><style face="normal" font="default" size="100%">Yue, Yanni</style></author><author><style face="normal" font="default" size="100%">Xinyuan Fan*</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Visible light-mediated cross-coupling of electrophiles: synthesis of α-amino amides from isocyanates and ketimines</style></title><secondary-title><style face="normal" font="default" size="100%">Organic Chemistry FrontiersOrganic Chemistry Frontiers</style></secondary-title><short-title><style face="normal" font="default" size="100%">Org. Chem. Front.</style></short-title></titles><dates><year><style  face="normal" font="default" size="100%">2021</style></year></dates><number><style face="normal" font="default" size="100%">6</style></number><publisher><style face="normal" font="default" size="100%">The Royal Society of Chemistry</style></publisher><volume><style face="normal" font="default" size="100%">8</style></volume><pages><style face="normal" font="default" size="100%">1227-1232</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">A catalytic system to synthesize α-amino amides from isocyanates and ketimines has been developed using visible light iridium photoredox catalysis via umpolung reactivity of ketimines. Cross-couplings between diverse ketimine and isocyanate substrates have been evaluated, affording the desired α-amino amide products in good yields. In addition, a metal-free catalytic system using perylene and N,N-diisopropylethylamine has been developed. Finally, single-step synthesis of the psychoactive drug benzodiazepine-2-one analogue from one of the coupling products has been achieved, indicating the great application potential of the synthetic method developed herein.</style></abstract><work-type><style face="normal" font="default" size="100%">10.1039/D0QO01620A</style></work-type></record></records></xml>