<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Robinson, J. R.</style></author><author><style face="normal" font="default" size="100%">Yadav, J.</style></author><author><style face="normal" font="default" size="100%">Fan, X. Y.</style></author><author><style face="normal" font="default" size="100%">Stanton, G. R.</style></author><author><style face="normal" font="default" size="100%">Schelter, E. J.</style></author><author><style face="normal" font="default" size="100%">Pericas, M. A.</style></author><author><style face="normal" font="default" size="100%">Walsh, P. J.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Non-Covalent Immobilization of Rare Earth Heterobimetallic Frameworks and their Reactivity in an Asymmetric Michael Addition</style></title><secondary-title><style face="normal" font="default" size="100%">Advanced Synthesis &amp;amp; CatalysisAdvanced Synthesis &amp;amp; Catalysis</style></secondary-title><alt-title><style face="normal" font="default" size="100%">Adv Synth Catal</style></alt-title><short-title><style face="normal" font="default" size="100%">Adv. Synth. Catal.</style></short-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">alpha,beta-unsaturated ketones</style></keyword><keyword><style  face="normal" font="default" size="100%">asymmetric catalysis</style></keyword><keyword><style  face="normal" font="default" size="100%">chiral lanthanide complexes</style></keyword><keyword><style  face="normal" font="default" size="100%">continuous-flow</style></keyword><keyword><style  face="normal" font="default" size="100%">convey asymmetry</style></keyword><keyword><style  face="normal" font="default" size="100%">enantioselective epoxidation</style></keyword><keyword><style  face="normal" font="default" size="100%">heterobimetallic complexes</style></keyword><keyword><style  face="normal" font="default" size="100%">michael addition</style></keyword><keyword><style  face="normal" font="default" size="100%">nitroaldol reaction</style></keyword><keyword><style  face="normal" font="default" size="100%">organic-synthesis</style></keyword><keyword><style  face="normal" font="default" size="100%">rare earths</style></keyword><keyword><style  face="normal" font="default" size="100%">ring-opening reactions</style></keyword><keyword><style  face="normal" font="default" size="100%">solid-phase synthesis</style></keyword><keyword><style  face="normal" font="default" size="100%">substrate-binding</style></keyword><keyword><style  face="normal" font="default" size="100%">supported catalysts</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2014</style></year><pub-dates><date><style  face="normal" font="default" size="100%">Apr 14</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">6</style></number><volume><style face="normal" font="default" size="100%">356</style></volume><pages><style face="normal" font="default" size="100%">1243-1254</style></pages><isbn><style face="normal" font="default" size="100%">1615-4150</style></isbn><language><style face="normal" font="default" size="100%">English</style></language><abstract><style face="normal" font="default" size="100%">Heterobimetallic Lewis acid catalysts are broadly useful and methods to recycle them have immediate applications. However, their immobilization through covalent binding can be challenging. Non-covalent immobilization of supported asymmetric catalysts is attractive due to ease of preparation and potential for reversible binding. We report a novel non-covalent binding strategy for Shibasaki&amp;#039;s REMB framework {RE=rare earth metal; M=Li, Na, K; B=BINOL; RE:M:B=1:3:3, [M-3(sol)(n)][(BINOLate)(3)RE]} and explore the reactivity of the supported catalyst.</style></abstract><accession-num><style face="normal" font="default" size="100%">WOS:000334241600011</style></accession-num><notes><style face="normal" font="default" size="100%">Ae8hwTimes Cited:1Cited References Count:99</style></notes><auth-address><style face="normal" font="default" size="100%">Univ Penn, Dept Chem, P Roy &amp;amp; Diana T Vagelos Labs, Philadelphia, PA 19104 USAInst Chem Res Catalonia ICIQ, Tarragona 43007, SpainUniv Barcelona, Dept Quim Organ, E-08028 Barcelona, Spain</style></auth-address></record></records></xml>