<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Sun, Jiaxing</style></author><author><style face="normal" font="default" size="100%">Lei Liu</style></author><author><style face="normal" font="default" size="100%">Liang Xu</style></author><author><style face="normal" font="default" size="100%">Wang, Yuanyuan</style></author><author><style face="normal" font="default" size="100%">Zhijun Wu</style></author><author><style face="normal" font="default" size="100%">Min Hu</style></author><author><style face="normal" font="default" size="100%">Shi, Zongbo</style></author><author><style face="normal" font="default" size="100%">Yongjie Li</style></author><author><style face="normal" font="default" size="100%">Zhang, Xiaoye</style></author><author><style face="normal" font="default" size="100%">Jianmin Chen</style></author><author><style face="normal" font="default" size="100%">Weijun Li</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Key Role of Nitrate in Phase Transitions of Urban Particles: Implications of Important Reactive Surfaces for Secondary Aerosol Formation</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of Geophysical Research: AtmospheresJournal of Geophysical Research: Atmospheres</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">deliquescence relative humidity</style></keyword><keyword><style  face="normal" font="default" size="100%">haze formation</style></keyword><keyword><style  face="normal" font="default" size="100%">heterogeneous reaction</style></keyword><keyword><style  face="normal" font="default" size="100%">Hygroscopicity</style></keyword><keyword><style  face="normal" font="default" size="100%">individual particles</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2018</style></year><pub-dates><date><style  face="normal" font="default" size="100%">2018/01/27</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">2</style></number><publisher><style face="normal" font="default" size="100%">John Wiley &amp;amp; Sons, Ltd</style></publisher><volume><style face="normal" font="default" size="100%">123</style></volume><pages><style face="normal" font="default" size="100%">1234-1243</style></pages><isbn><style face="normal" font="default" size="100%">2169-897X</style></isbn><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">Abstract Ammonium sulfate (AS) and ammonium nitrate (AN) are key components of urban fine particles. Both field and model studies showed that heterogeneous reactions of SO2, NO2, and NH3 on wet aerosols accelerated the haze formation in northern China. However, little is known on phase transitions of AS-AN containing haze particles. Here hygroscopic properties of laboratory-generated AS-AN particles and individual particles collected during haze events in an urban site were investigated using an individual particle hygroscopicity system. AS-AN particles showed a two-stage deliquescence at mutual deliquescence relative humidity (MDRH) and full deliquescence relative humidity (DRH) and three physical states: solid before MDRH, solid-aqueous between MDRH and DRH, and aqueous after DRH. During hydration, urban haze particles displayed a solid core and aqueous shell at RH = 60?80% and aqueous phase at RH &amp;gt; 80%. Most particles were in aqueous phase at RH &amp;gt; 50% during dehydration. Our results show that AS content in individual particles determines their DRH and AN content determines their MDRH. AN content increase can reduce MDRH, which indicates occurrence of aqueous shell at lower RH. The humidity-dependent phase transitions of nitrate-abundant urban particles are important to provide reactive surfaces of secondary aerosol formation in the polluted air.</style></abstract><access-date><style face="normal" font="default" size="100%">2019/02/14</style></access-date></record></records></xml>