@article {14175,
	title = {Cloud droplet activation of mixed organic-sulfate particles produced by the photooxidation of isoprene},
	journal = {Atmospheric Chemistry and Physics},
	volume = {10},
	number = {8},
	year = {2010},
	note = {ISI Document Delivery No.: 589WRTimes Cited: 0Cited Reference Count: 70King, S. M. Rosenoern, T. Shilling, J. E. Chen, Q. Wang, Z. Biskos, G. McKinney, K. A. Poeschl, U. Martin, S. T.Office of Science (BES), US Department of Energy [DE-FG02-08ER64529]; EPA STAR ; Harvard University ; Danish Agency for Science Technology and Innovation [272-06-0318]; NASA ; ACIThis material is based upon work supported by the Office of Science (BES), US Department of Energy, Grant No. DE-FG02-08ER64529. SMK acknowledges support from the EPA STAR fellowship program and from the Harvard University DRCLAS Jorge Paulo Lemann Fellowship. TR acknowledges support from the Danish Agency for Science Technology and Innovation under Grant No. 272-06-0318. QC acknowledges support from the NASA Earth and Space Science Fellowship. JES acknowledges support from the ACI. The authors thank J. Kroll for helpful discussion.Copernicus gesellschaft mbhGottingen},
	pages = {3953-3964},
	type = {Article},
	abstract = {The cloud condensation nuclei (CCN) properties of ammonium sulfate particles mixed with organic material condensed during the hydroxyl-radical-initiated photooxidation of isoprene (C5H8) were investigated in the continuous-flow Harvard Environmental Chamber. CCN activation curves were measured for organic particle mass concentrations of 0.5 to 10.0 mu g m(-3), NOx concentrations from under 0.4 ppbv up to 38 ppbv, particle mobility diameters from 70 to 150 nm, and thermodenuder temperatures from 25 to 100 degrees C. At 25 degrees C, the observed CCN activation curves were accurately described by a Kohler model having two internally mixed components, namely ammonium sulfate and secondary organic material. The modeled physicochemical parameters of the organic material were equivalent to an effective hygroscopicity parameter kappa(ORG) of 0.10 +/- 0.03, regardless of the C5H8:NOx concentration ratio for the span of \&gt; 200:0.4 to 50:38 (ppbv:ppbv). The volatilization curves (i.e., plots of the residual organic volume fraction against temperature) were also similar for the span of investigated C5H8:NOx ratios, suggesting a broad similarity of particle chemical composition. This suggestion was supported by limited variance at 25 degrees C among the particle mass spectra. For example, the signal intensity at m/z 44 (which can result from the fragmentation of oxidized molecules believed to affect hygroscopicity and CCN properties) varied weakly from 6 to 9\% across the range of investigated conditions. In contradistinction to the results for 25 degrees C, conditioning up to 100 degrees C in the thermodenuder significantly reduced CCN activity. The altered CCN activity might be explained by chemical reactions (e.g., decomposition or oligomerization) of the secondary organic material at elevated temperatures. The study{\textquoteright}s results at 25 degrees C, in conjunction with the results of other chamber and field studies for a diverse range of conditions, suggest that a value of 0.10 +/- 0.05 for kappa(ORG) is representative of both anthropogenic and biogenic secondary organic material. This finding supports the use of kappa(ORG) as a simplified yet accurate general parameter to represent the CCN activation of secondary organic material in large-scale atmospheric and climate models.},
	keywords = {aerosol soa formation, alpha-pinene, ammonium-sulfate, atmospheric aerosol, ccn activation, condensation nuclei, hygroscopic growth, trace gases, volatility measurements, water-vapor},
	isbn = {1680-7316},
	author = {King, S. M. and Rosenoern, T. and Shilling, J. E. and Q. Chen and Z. Wang and Biskos, G. and McKinney, K. A. and P{\"o}schl, U. and Martin, S. T.}
}
