@article {14157,
	title = {Characterization of a real-time tracer for isoprene epoxydiols-derived secondary organic aerosol (IEPOX-SOA) from aerosol mass spectrometer measurements},
	journal = {Atmospheric Chemistry and Physics},
	volume = {15},
	number = {20},
	year = {2015},
	note = {ISI Document Delivery No.: CV5NETimes Cited: 1Cited Reference Count: 102Hu, W. W. Campuzano-Jost, P. Palm, B. B. Day, D. A. Ortega, A. M. Hayes, P. L. Krechmer, J. E. Chen, Q. Kuwata, M. Liu, Y. J. de Sa, S. S. McKinney, K. Martin, S. T. Hu, M. Budisulistiorini, S. H. Riva, M. Surratt, J. D. St Clair, J. M. Isaacman-Van Wertz, G. Yee, L. D. Goldstein, A. H. Carbone, S. Brito, J. Artaxo, P. de Gouw, J. A. Koss, A. Wisthaler, A. Mikoviny, T. Karl, T. Kaser, L. Jud, W. Hansel, A. Docherty, K. S. Alexander, M. L. Robinson, N. H. Coe, H. Allan, J. D. Canagaratna, M. R. Paulot, F. Jimenez, J. L.NSF [AGS-1243354, AGS-1360834, AGS-1250569]; NASA [NNX12AC03G, NNX12AC06G]; DOE (BER/ASR) [DE-SC0011105]; NOAA [NA13OAR4310063]; EPA STAR [FP-91761701-0, FP-91770901-0]; CIRES; DOE SCGF (ORAU/ORISE) fellowship; Austrian Federal Ministry for Transport, Innovation and Technology (BMVIT) through Austrian Space Applications Programme (ASAP) of Austrian Research Promotion Agency (FFG); Visiting Scientist Program at National Institute of Aerospace (NIA); NSF Fellowship [DGE-1106400]; FAPESP [2013/05014-0, 2014/05238-8]; CNPq [457843/2013-6, 307160/2014-9]; US Environmental Protection Agency (EPA) [835404]; Electric Power Research Institute (EPRI); UK Natural Environment Research Council through OP3; SAMBBA projects [NE/D002117/1, NE/J010073/1]This study was partially supported by NSF AGS-1243354 and AGS-1360834, NASA NNX12AC03G, DOE (BER/ASR) DE-SC0011105, and NOAA NA13OAR4310063. B. Palm and J. Krechmer are grateful for fellowships from EPA STAR (FP-91761701-0 and FP-91770901-0) and CIRES. A. Ortega is grateful for a CU-Boulder Chancellor{\textquoteright}s and DOE SCGF (ORAU/ORISE) fellowship. A. Wisthaler and T. Mikoviny were supported by the Austrian Federal Ministry for Transport, Innovation and Technology (BMVIT) through the Austrian Space Applications Programme (ASAP) of the Austrian Research Promotion Agency (FFG), and the Visiting Scientist Program at the National Institute of Aerospace (NIA). G. Isaacman-VanWertz is grateful for an NSF Fellowship (DGE-1106400). U. C. Berkeley was supported by NSF AGS-1250569. We acknowledge the logistical support from the LBA Central Office at INPA (Instituto Nacional de Pesquisas da Amazonia). P. Artaxo acknowledges support from FAPESP grants 2013/05014-0 and 2014/05238-8 and CNPq support from grants 457843/2013-6 and 307160/2014-9. We acknowledges this work was funded by the US Environmental Protection Agency (EPA) through grant number 835404. The contents of this publication are solely the responsibility of the authors and do not necessarily represent the official views of the US EPA. Further, the US EPA does not endorse the purchase of any commercial products or services mentioned in the publication. The US EPA through its Office of Research and Development collaborated in the research described here. It has been subjected to agency review and approved for publication, but may not necessarily reflect social agency policy. The authors would also like to thank the Electric Power Research Institute (EPRI) for their support. M. Riva and J. D. Surratt wish to thank the Camille and Henry Dreyfus Postdoctoral Fellowship Program in Environmental Chemistry for their financial support. We thank J. Crounse and P. Wennberg from Caltech for gas-phase IEPOX data in SOAS-CTR and DC3, under support from NASA NNX12AC06G. We thank Lu Xu and Nga Lee Ng from Georgia Tech for providing data from their studies. We acknowledge funding from the UK Natural Environment Research Council through the OP3 and SAMBBA projects (grant refs. NE/D002117/1 and NE/J010073/1).Copernicus gesellschaft mbhGottingen},
	pages = {11807-11833},
	type = {Article},
	abstract = {Substantial amounts of secondary organic aerosol (SOA) can be formed from isoprene epoxydiols (IEPOX), which are oxidation products of isoprene mainly under low-NO conditions. Total IEPOX-SOA, which may include SOA formed from other parallel isoprene oxidation pathways, was quantified by applying positive matrix factorization (PMF) to aerosol mass spectrometer (AMS) measurements. The IEPOX-SOA fractions of organic aerosol (OA) in multiple field studies across several continents are summarized here and show consistent patterns with the concentration of gas-phase IEPOX simulated by the GEOS-Chem chemical transport model. During the Southern Oxidant and Aerosol Study (SOAS), 78\% of PMF-resolved IEPOX-SOA is accounted by the measured IEPOX-SOA molecular tracers (2-methyltetrols, C5-Triols, and IEPOX-derived organosulfate and its dimers), making it the highest level of molecular identification of an ambient SOA component to our knowledge. An enhanced signal at C5H6O+ (m/z 82) is found in PMF-resolved IEPOX-SOA spectra. To investigate the suitability of this ion as a tracer for IEPOX-SOA, we examine fC(5)H(6)O (fC(5)H(6)O = C5H6O+ / OA) across multiple field, chamber, and source data sets. A background of similar to 1.7 +/- 0.1 parts per thousand (parts per thousand = parts per thousand) is observed in studies strongly influenced by urban, biomass-burning, and other anthropogenic primary organic aerosol (POA). Higher background values of 3.1 +/- 0.6 parts per thousand are found in studies strongly influenced by monoterpene emissions. The average laboratory monoterpene SOA value (5.5 +/- 2.0 parts per thousand) is 4 times lower than the average for IEPOX-SOA (22 +/- 7 parts per thousand), which leaves some room to separate both contributions to OA. Locations strongly influenced by isoprene emissions under low-NO levels had higher fC(5)H(6)O (similar to 6.5 +/- 2.2 parts per thousand on average) than other sites, consistent with the expected IEPOX- SOA formation in those studies. fC(5)H(6)O in IEPOX- SOA is always elevated (12-40 parts per thousand) but varies substantially between locations, which is shown to reflect large variations in its detailed molecular composition. The low fC(5)H(6)O (\&lt; 3 parts per thousand) reported in non-IEPOX-derived isoprene-SOA from chamber studies indicates that this tracer ion is specifically enhanced from IEPOX- SOA, and is not a tracer for all SOA from isoprene. We introduce a graphical diagnostic to study the presence and aging of IEPOX- SOA as a triangle plot of f(CO2) vs. fC(5)H(6)O. Finally, we develop a simplified method to estimate ambient IEPOX- SOA mass concentrations, which is shown to perform well compared to the full PMF method. The uncertainty of the tracer method is up to a factor of similar to 2, if the fC(5)H(6)O of the local IEPOX- SOA is not available. When only unit mass-resolution data are available, as with the aerosol chemical speciation monitor (ACSM), all methods may perform less well because of increased interferences from other ions at m/z 82. This study clarifies the strengths and limitations of the different AMS methods for detection of IEPOX- SOA and will enable improved characterization of this OA component.},
	keywords = {anthropogenic emissions, biomass-burning, catalyzed reactive uptake, chemical-characterization, fine-particle composition, high-resolution, particulate matter, photooxidation products, smoke, source apportionment, submicron particles},
	isbn = {1680-7316},
	author = {Hu, W. W. and Campuzano-Jost, P. and Palm, B. B. and Day, D. A. and Ortega, A. M. and Hayes, P. L. and Krechmer, J. E. and Q. Chen and Kuwata, M. and Liu, Y. J. and de Sa, S. S. and McKinney, K. and Martin, S. T. and Hu, M. and Budisulistiorini, S. H. and Riva, M. and Surratt, J. D. and St Clair, J. M. and Isaacman-Van Wertz, G. and Yee, L. D. and Goldstein, A. H. and Carbone, S. and Brito, J. and Artaxo, P. and de Gouw, J. A. and Koss, A. and Wisthaler, A. and Mikoviny, T. and Karl, T. and Kaser, L. and Jud, W. and Hansel, A. and Docherty, K. S. and Alexander, M. L. and Robinson, N. H. and Coe, H. and Allan, J. D. and Canagaratna, M. R. and Paulot, F. and Jimenez, J. L.}
}
