Per-and polyfluoroalkyl substances (PFASs) are manmade chemicals that have wide industrial and commercial application. However, little research has been carried out on PFASs pollution in groundwater from a previously contaminated site. Here, we investigated 43 PFASs in a monitoring campaign from two different aquifers in the North China Plain. Our results revealed that total PFASs concentrations ( n-ary sumation 43PFASs) ranged from 0.22 to 3,776.76 ng/L, with no spatial or compositional differences. Moreover, perfluorooctanoic acid (PFOA) and perfluoroheptane sulfonate (PFHpS) were the dominant pollutants with mean concentrations of 177.33 ng/L and 51 ng/L, respectively. n-ary sumation 43PFAS decreased with well depth due to the adsorption of PFASs to the aquifer materials. Water temperature, total organic carbon, dissolved oxygen, and total phosphorus concentrations were correlated to the PFAS concentrations. Principal component analysis indicated that the main sources of PFASs in groundwater were untreated industrial discharge, untreated domestic wastewater, food packaging, aqueous film forming foams and metal plating, and surface runoff, which overlapped with the industries that previously existed in a nearby city. Human health risks from drinking contaminated groundwater were low to the local residents, with children aged 1-2 years being the most sensitive group. One specific site with a high PFOA concentration was of concern, as it was several orders higher than the 70 ng/L recommended by US Environmental Protection Agency health advisory. This study provided baseline data for PFASs in a previously contaminated site, which will help in the development of effective strategies for controlling PFASs pollution in the North China Plain.
Particulate matter (PM) and gaseous hydrogen peroxide (H2O2) interact ubiquitously to influence atmospheric oxidizing capacity. However, quantitative information on H2O2 loss and its fate on urban aerosols remain unclear. This study investigated the kinetics of heterogeneous reactions of H2O2 on PM2.5, and explored how these processes are affected by various experimental conditions (i.e., relative humidity, temperature, and H2O2 concentration). We observed a persistent uptake of H2O2 by PM2.5 (with the uptake coefficients (γ) of 10-4 to 10-3), exacerbated by aerosol liquid water and temperature, confirming the critical role of water-assisted chemical decomposition during the uptake process. A positive correlation between the γ values and the ratio of dissolved iron concentration to H2O2 concentration suggests that a Fenton catalytic decomposition may be an important pathway for H2O2 conversion on PM2.5 under dark conditions. Furthermore, on the basis of kinetic data gained, the parameterization of H2O2 uptake on PM2.5 was developed, and was applied into a box model. The good agreement between simulated and measured H2O2 uncovered the significant role that heterogeneous uptake plays in the sink of H2O2 in the atmosphere. These findings suggest that the composition-dependent particle reactivity toward H2O2 should be considered in atmospheric models for elucidating the environmental and health effects of H2O2 uptake by ambient aerosols.
Persulfate-based advanced oxidation processes (persulfate-AOPs) offer great promise for environmental remediation, with heterogeneous catalysts providing the backbone of many wastewater purification technologies. Unlike conventional nanocatalyst heterogeneous systems, the immobilized-catalyst system can bypass the separation problem to reduce scour and prevent aggregation by anchoring nanoparticles onto porous or large-particle carriers. This review presents the state-of-the-art of knowledge concerning immobilization methodologies and reactors, reaction mechanisms, and activation performance. Immobilization techniques onto supports are summarized and discussed, including membrane-based reaction systems (immersion mode, and filtration mode), electrocatalytic auxiliary systems, and alternative supports (metallic glasses, aerogels, hydrogels, and specific materials). Key scientific problems and important prospects for the further development of immobilized catalysts are outlined.
Energy-efficient components that are capable of intelligently regulating room temperature are much demanded to reduce the energy consumption in buildings. In recent years, phase change materials (PCMs) have been widely investigated for intelligent temperature regulation by taking advantages of their unique thermal, optical, and mechanical properties across phase transition. In this review, we summarize the mechanisms of PCMs for intelligent temperature regulation, including latent heat, optical modulation, and mechanical deformation. We then discuss the traditional PCMs, such as organic and inorganic PCMs with huge latent heats, and emerging PCMs, such as VO2, for the applications in temperature controls, smart windows, and radiative cooling surfaces. We finally point out where to focus for these PCMs to realize applications in buildings. This review provides insights into future research of PCMs for their intelligent applications.