Conversion of digestate into biochar-based catalysts is an effective strategy for disposal and resource utilization. The active sites on biochar correlated with reactive species formation in peroxymonosulfate (PMS) system directly. Clarifying the structure-performance relationship of digestate derived biochar in PMS system was essential for decomposition of contaminants. Herein, dairy manure digestate derived biochar (DMDB) was prepared for PMS activation and sulfamethoxazole (SMX) degradation. The higher pyrolysis temperature could promote effective sites generation. Especially, the DMDB-800 catalyst exhibited excellent performance for PMS activation, achieving 90.2% degradation of SMX within 60 min. Based on the correlation analysis between log (k) values and active sites, defects, graphite N and CO were identified as dominant sites for PMS activation. The 1O2 oxidation and surface electron transfer were critical routes for SMX degradation. Besides, the degradation pathways of SMX were proposed according to DFT calculations and intermediates determination. The cleavage of the sulfonamide bond, hydroxylation of the benzene ring and oxidation of the amino group mainly occurred during SMX degradation. Overall, this study provides deep insights into the enhanced mechanism of tunable active sites on DMDBs for PMS activation, boosting the application of digestate biochar for water treatment in advanced oxidation systems.
ABSTRACT Numerous approaches have been used to modify graphitic carbon nitride (g-C3N4) for improving its photocatalytic activity. In this study, we demonstrated a facial post-calcination method for modified graphitic carbon nitride (g-C3N4-Ar/Air) to direct tuning band structure, i.e., bandgap and positions of conduction band (CB)/valence band (VB), through the control of atmospheric condition without involving any additional elements or metals or semiconductors. The synthesized g-C3N4-Ar/Air could efficiently degrade sulfamethazine (SMT) under simulated solar light, i.e., 99.0% removal of SMT with rate constant k1 = 2.696 h−1 within 1.5 h (4.9 times than pristine g-C3N4). Material characterizations indicated that the damaged/partial-collapsed structure and decreased nanosheet-interlayer distance for g-C3N4-Ar/Air resulted in the shift of band structure due to the denser stacking of pristine g-C3N4 through oxidative exfoliation and planarization by air calcination. In addition, the bandgap of g-C3N4-Ar/Air was slightly shrunk from 2.82 eV (pristine g-C3N4) to 2.79 eV, and the CB was significantly upshifted from −0.44 eV (pristine g-C3N4) to −0.81 eV, suggesting the powerful ability for donating the electrons for O2 to form •O2−. Fukui index (f –) based on theoretical calculation indicated that the sites of SMT molecule with high values, i.e., N9, C4 and C6, preferred to be attacked by •O2− and •OH, which is confirmed by the intermediates’ analysis. The tuning method for graphitic carbon nitride provides a simple approach to regulate the charge carrier lifetime then facilitate the utilization efficiency of solar light, which exhibits great potential in efficient removal of emerging organic contaminants from wastewater.
A novel g-C3N5/Bi4O5Br2 surface heterojunction was developed via in-situ growth of Bi-rich Bi4O5Br2 on g-C3N5 nanosheets. The optimal composite achieved 3.6- and 16.0- times of sulfathiazole (STZ) degradation activity when compared with pristine Bi4O5Br2 and g-C3N5. The interlayer stacking morphology and extra nitrogen in triazine units significantly narrowed the conduction band of g-C3N5, which greatly promoted its visible utilization; while the bismuth-rich property of Bi4O5Br2 prolonged the excited charge carrier lifetime. Both photoluminescence and electrochemical impedance spectroscopy analysis demonstrated that the type-II surface heterojunction (g-C3N5/Bi4O5Br2) offered remarkable charge transfer and separation due to the matched energy band structure. The STZ degradation mechanism and pathways were proposed based on experiments and density functional theory calculation, and the contribution of reactive species for STZ degradation followed the order of O2∙- > h+ > OH. Moreover, the toxicity evolution of STZ was evaluated, suggesting that sufficient mineralization is required to ensure safe discharge. The Box-Behnken experimental design methodology study revealed that g-C3N5/Bi4O5Br2 exhibited high reactivity for antibiotics degradation under different water matrix. This study suggested that g-C3N5/Bi4O5Br2 has great application potential for cost-effective remediation of persistent organic contaminants by using solar light.
Forecasting is an indispensable element of operational research (OR) and an important aid to planning. The accurate estimation of the forecast uncertainty facilitates several operations management activities, predominantly in supporting decisions in inventory and supply chain management and effectively setting safety stocks. In this paper, we introduce a feature-based framework, which links the relationship between time series features and the interval forecasting performance into providing reliable interval forecasts. We propose an optimal threshold ratio searching algorithm and a new weight determination mechanism for selecting an appropriate subset of models and assigning combination weights for each time series tailored to the observed features. We evaluate our approach using a large set of time series from the M4 competition. Our experiments show that our approach significantly outperforms a wide range of benchmark models, both in terms of point forecasts as well as prediction intervals.
Growing national decarbonization commitments require rapid and deep reductions of carbon dioxide emissions from existing fossil-fuel power plants. Although retrofitting existing plants with carbon capture and storage or biomass has been discussed extensively, yet such options have failed to provide evident emission reductions at a global scale so far. Assessments of decarbonization technologies tend to focus on one specific option but omit its interactions with competing technologies and related sectors (e.g., water, food, and land use). Energy system models could mimic such inter-technological and inter-sectoral competition but often aggregate plant-level parameters without validation, as well as fleet-level inputs with large variability and uncertainty. To enhance the accuracy and reliability of top-down optimization models, bottom-up plant-level experience accumulation is of vital importance. Identifying sweet spots for plant-level pilot projects, overcoming the technical, financial, and social obstacles of early large-scale demonstration projects, incorporating equity into the transition, propagating the plant-level potential to generate fleet-level impacts represent some key complexity of existing fossil-fuel power plant decarbonization challenges that imposes the need for a serious re-evaluation of existing fossil fuel power plant abatement in energy transition.
Photocatalytic efficiency toward volatile organic compounds (VOCs) decomposition has crucially relied on the nature of their stereochemical structures, in which the complicated decomposition mechanism has not been unveiled. As typical cases of VOCs pollutants, m-, p-, and o-xylene isomers share the identical molecular formula with discrepant methyl positions at the benzene ring. The essential contribution of the methyl position to the decomposition mechanism of xylene isomers, especially the rate-determining step for benzene ring-opening, is unraveled in this work. It is identified that the decomposition rate of xylene isomers on the SnO2 catalyst is decreased in the order of o-xylene > m-xylene ≈ p-xylene. The durability of SnO2 photocatalyst is also accomplished for a superior o-xylene decomposition performance. By combining the experimental and theoretical investigation, it is manifested that the regulation of methyl positions in the ortho-sites is an appealing route for reducing the ring-opening energy barriers and guiding the complete mineralization of the hazardous xylene. This work could provide insights into unraveling the unique role of the stereochemical structure of xylene on ring-opening barriers for efficient and stable VOC decomposition.
The massive use of antibiotics has led to their omnipresence in aquatic environments, and the photodegradation was found to be the dominant transformation process for antibiotics in the natural river system. Herein, we investigated the photodegradation kinetics of 77 antibiotics in 7 classes in water under simulated sunlight. Using the quantum chemical descriptors predicted by the density functional theory calculation, the quantitative structure-activity relationship (QSAR) models were established to explore the main chemical descriptors determining the photodegradation of antibiotics. The results showed that the photodegradation kinetics of antibiotics conformed to the pseudo-first order kinetic model. The photodegradation rate constants of different antibiotics varied 4 orders of magnitude, and the photodegradation rate constants of quinolones were significantly higher than those for other classes of antibiotics due to the F atoms in their molecular structures. The developed QSAR models revealed that the energy gap (Egap) between ELUMO and EHOMO was the main chemical descriptor determining the photodegradation of antibiotics, and it was negatively correlated with lgk. In addition, the number of F atom was also included in the QSAR models due to the great contribution of F atom to the direct photolysis of quinolones. This study ordered the photodegradation rate constants of 77 antibiotics, and revealed the major chemical descriptors determining the photodegradation of antibiotics. The results provide the basic information for the photolysis of antibiotics, which is significant for predicting the environmental behaviors and evaluating the ecological risks of antibiotics in aquatic environments.
Though metal resistance genes (MRGs) are of global concern in aquatic ecosystems, the underlying factors responsible for MRGs dissemination, especially in urban rivers on the vulnerable Qinghai-Tibet Plateau, are rarely known. Here, we collected 64 samples including water and sediments during the wet and dry seasons and effluents from six wastewater treatment plants (WWTPs) during the dry season and measured 50 metal(loid)s, 60 bacterial phyla, and 259 MRGs. We observed the distinct difference of metal(loid)s, bacterial communities, and MRGs between water and sediments and the great seasonal changes in metal(loid)s and bacterial communities instead of MRGs. Thirty-one metal(loid)s were detectable in the water, with relatively low concentrations and no significant effects on the planktonic bacterial communities and MRGs. Interestingly, the WWTPs effluent partially promoted the prevalence of dissolved metal(loid)s, bacterial communities, and MRGs along the river. In the sediments, the average concentrations of 17 metal(loid)s exceeded their corresponding background levels in this region and strongly influenced the bacterial communities and the MRGs. Sedimentary Hg and Cd, mainly sourced from the intensive animal husbandry, were the major pollutants causing ecological risks and largely shaped their corresponding resistomes. Moreover, we found that bacterial communities predominantly determined the variation of MRGs in both water and sediments. Metagenome-assembled genomes further reveals the widespread co-occurrence of MRGs and antibiotic resistance genes (ARGs) in MRG hosts. Our study highlighted the concern of effluents discharged from WWTPs and emphasized the importance of controlling the anthropogenic inputs of sedimentary metal(loid)s in the plateau river ecosystems.