A deep-blue emitter 1-(10-(4-methoxyphenyl) anthracen-9-yl)-4-(10-(4-cyanophenyl) anthracen-9yl) tetraphenylethene (TPEA) has been successfully prepared by a combinational molecular design, which contains triplet-triplet fusion (TTF) and hybridized local charge transfer (HLCT) characteristics to increase the ratio of triplet excitons used. The tetraphenylethene (TPE) moiety contributes the emitter with an aggregation-induced emission (AIE) property to enhance the solid-state luminescence efficiency. The crystallographic structure shows that the two anthracene groups are twisted from the central TPE moiety, which effectively prevents a bathochromic shift of the emission. In addition, we adopted a donor-acceptor (D-A) structure to improve the charge balance in organic light-emitting diodes (OLEDs). The material possesses high thermal stability with a glass transition temperature (Tg) of 155 1C. Based on all these advantages, a high performance of the non-doped device was achieved with a turnon voltage (Von) of 2.6 V at a luminance of 1 cd m(-2), a maximum power efficiency (ZPE, max) of 11.1 lm W-1, a maximum current efficiency (ZCE, max) of 9.9 cd A(-1), and a low current efficiency roll-off even at 1000 cd m(-2). Moreover, a deep-blue emission with Commission Internationale de l'E ` clairage (CIE) coordinates of (0.15, 0.09), a maximum external quantum efficiency (Zext, max) of 8.0% and the highest ZPE, max of 7.3 lm W-1 among all the TTF and HLCT deep-blue emitters were obtained by doping TPEA into the host of bis-4-[(N-carbazolyl) phenyl]-phenylphosphine oxide (BCPO). These results indicate that the combinational molecular design is promising for highly efficient deep-blue emitters.
High-efficiency particulate air (HEPA) filtration in combination with an electrostatic precipitator (ESP) can be a cost-effective approach to reducing indoor particulate exposure, but ESPs produce ozone. The health effect of combined ESP-HEPA filtration has not been examined. We conducted an intervention study in 89 volunteers. At baseline, the air-handling units of offices and residences for all subjects were comprised of coarse, ESP, and HEPA filtration. During the 5-week long intervention, the subjects were split into 2 groups, 1 with just the ESP removed and the other with both the ESP and HEPA removed. Each subject was measured for cardiopulmonary risk indicators once at baseline, twice during the intervention, and once 2 weeks after baseline conditions were restored. Measured indoor and outdoor PM2.5 and ozone concentrations, coupled with time-activity data, were used to calculate exposures. Removal of HEPA filters increased 24-hour mean PM2.5 exposure by 38 (95% CI: 31, 45) mug/m(3) . Removal of ESPs decreased 24-hour mean ozone exposure by 2.2 (2.0, 2.5) ppb. No biomarkers were significantly associated with HEPA filter removal. In contrast, ESP removal was associated with a -16.1% (-21.5%, -10.4%) change in plasma-soluble P-selectin and a -3.0% (-5.1%, -0.8%) change in systolic blood pressure, suggesting reduced cardiovascular risks.
We focus on the COM-type negative binomial distribution with three parameters, which belongs to COM-type (a, b, 0) class distributions and family of equilibrium distributions of arbitrary birth-death process. Besides, we show abundant distributional properties such as overdispersion and underdispersion, log-concavity, log-convexity (infinite divisibility), pseudo compound Poisson, stochastic ordering, and asymptotic approximation. Some characterizations including sum of equicorrelated geometrically distributed random variables, conditional distribution, limit distribution of COM-negative hypergeometric distribution, and Stein’s identity are given for theoretical properties. COM-negative binomial distribution was applied to overdispersion and ultrahigh zero-inflated data sets. With the aid of ratio regression, we employ maximum likelihood method to estimate the parameters and the goodness-of-fit are evaluated by the discrete Kolmogorov-Smirnov test.
Plume rise parameterizations calculate the rise of pollutant plumes due to effluent buoyancy and exit momentum. Some form of these parameterizations is used by most air quality models. In this paper, the performance of the commonly used Briggs plume rise algorithm was extensively evaluated, through a comparison of the algorithm's results when driven by meteorological observations with direct observations of plume heights in the Athabasca oil sands region. The observations were carried out as part of the Canada-Alberta Joint Oil Sands Monitoring Plan in August and September of 2013. Wind and temperature data used to drive the algorithm were measured in the region of emissions from various platforms, including two meteorological towers, a radio-acoustic profiler, and a research aircraft. Other meteorological variables used to drive the algorithm include friction velocity, boundary-layer height, and the Obukhov length. Stack emissions and flow parameter information reported by continuous emissions monitoring systems (CEMSs) were used to drive the plume rise algorithm. The calculated plume heights were then compared to interpolated aircraft SO2 measurements, in order to evaluate the algorithm's prediction for plume rise. We demonstrate that the Briggs algorithm, when driven by ambient observations, significantly underestimated plume rise for these sources, with more than 50 % of the predicted plume heights falling below half the observed values from this analysis. With the inclusion of the effects of effluent momentum, the choice of different forms of parameterizations, and the use of different stability classification systems, this essential finding remains unchanged. In all cases, approximately 50 % or more of the predicted plume heights fall below half the observed values. These results are in contrast to numerous plume rise measurement studies published between 1968 and 1993. We note that the observations used to drive the algorithms imply the potential presence of significant spatial heterogeneity in meteorological conditions; we examine the potential impact of this heterogeneity in our companion paper (Akingunola et al., 2018). It is suggested that further study using long-term in situ measurements with currently available technologies is warranted to investigate this discrepancy, and that wherever possible, meteorological input variables are observed in the immediate vicinity of the emitting stacks.
Completely understanding the working mechanisms of sophisticated supramolecular self-assembly exhibiting competing paths is very important for chemists en route to acquiring the ability of constructing supramolecular systems with controlled structures and designed functions. Here, the self-aggregation behaviors of an N-heterocyclic aromatic dicarboximide molecule 1, boasting two competing paths that give rise to different supramolecular structures and exhibit distinct thermodynamic features, are carefully examined. First, a group of H-aggregates are observed when providing a medium driving force for aromatic stacking, and their formation is manifested as an anticooperative process. When exposed to enhanced strength of aromatic interactions, these H-aggregates are found to transform into J-aggregates via a cooperative assembly mechanism. With the assistance of a mathematic model accommodating two competing polymerization pathways, calculations are conducted to simulate and explain the thermodynamic equilibria of such a unique supramolecular system. The calculation results are highly consistent with the experimental observations, and some important properties are elucidated. Specifically, the anticooperative assembly mechanism generally promotes the formation of low to medium oligomers, whereas the cooperative path is more competent at producing high polymers. If the anticooperative and cooperative routes coexist and compete for the same molecule, the cooperative formations of high polymers are significantly suppressed unless a very high degree of polymerization can be achieved. Such a unique feature of concurring anticooperative and cooperative paths emerges to the H- and J-aggregates of molecule 1 and thus brings about the interesting sequential appearances of the two types of aggregates under conditions of continuously enlarged driving force for self-aggregation. Finally, based on the knowledge acquired from this study and by analyzing the steric features of 1 that influence its supramolecular packing motifs, a slightly modified molecular structure is designed, with which the intermediate H-aggregation state was successfully suppressed, and a single cooperative J-aggregation path is manifested.
Nanoelectronic devices with specifically designed structures for performance promotion or function expansion are of great interest, aiming for diversified advanced nanoelectronic systems. In this work, we report a dual-material gate (DMG) carbon nanotube (CNT) device with multiple functions, which can be configured either as a high-performance p-type field-effect transistor (FET) or a diode by changing the input manners of the device. When operating as a FET, the device exhibits a large current on/off ratio of more than 108 and a drain-induced barrier lowering of 97.3 mV V−1. When configured as a diode, the rectification ratio of the device can be greater than 105. We then demonstrate configurable analog and digital integrated circuits that are enabled by utilizing these devices. The configurability enables the realization of transformable functions in a single device or circuits, which gives future electronic systems the flexibility to adapt to the diverse requirements of their applications and/or ever-changing operating environments.
Worldwide there has been deterioration of lakeshore habitat and increasing eutrophication. These stresses have impacted littoral macroinvertebrate communities. However, bioassessment and rehabilitation have been largely carried out offshore, and the inshore macroinvertebrates have received less attention especially in shallow plateau lakes. In this study, we compared inshore and offshore macroinvertebrate communities in a shallow plateau lake, Lake Dianchi, China. The environmental parameters determining the distribution of macroinvertebrates were analyzed with partial redundancy analysis. Our results showed that macroinvertebrate communities differed significantly between inshore and offshore. Taxonomic richness was much higher inshore than offshore, due to higher habitat heterogeneity. By contrast, both density and biomass inshore were significantly lower than those of offshore. Generally, vegetation and substrate type were the key environmental parameters shaping macroinvertebrate communities. Eutrophication exerted great effect on offshore communities, while its impacts on inshore communities varied spatially. Shoreline degradation and seasonal eutrophication effects resulted in the limited density and biomass of inshore communities. Our results emphasized the significance of inshore habitats for macroinvertebrates in Lake Dianchi, and provided important implications for bioassessment and ecological rehabilitation in shallow lakes.
