Characterizing the kerogen-hosted pore structures is essential to understand the adsorption, transport and storage potential in organic-rich shale reservoirs. In this paper, we first separated the organic matter (kerogen) from the mineral matrix in four different shale samples of the Bakken Formation with different thermal maturities and then analyzed their chemical compositions using the wide-angle X-ray scattering (WAXS) method. Next, we acquired small-angle X-ray scattering (SAXS) to characterize the structure of the organic matter and see how these two will relate. The WAXS results showed that the isolated kerogens have high purity (free of inorganic minerals) and retain different chemical compositions. Moreover, SAXS analysis revealed that the isolated kerogens have similar radius of gyration (Rg) which is around 90 Å and the molecules are in the compact mode. Based on the pore size distribution analysis from the SAXS data, two main peaks were found in all of these four samples with one peak less than 40 Å and the other one larger than 1000 Å. Also, the TEM images revealed that Sample 1 is abundant in pores with sizes around 20 nm while Sample 2 does not have pores of that size, which agrees with the results from the pore size distribution that was obtained from the SAXS method. Ultimately, this study exhibits how different analytical instruments can provide us with useful information from complex structures of geomaterials. For all the samples, two main peaks can be found with one peak less than 40 Å and the other one larger than 1000 Å。
Quantifying the rhythms and rates of magmatic-hydrothermal systems is critical for a better understanding of their controls on ore formation and the dynamics of magmatic reservoirs that feed them. We reconstructed the evolution of ore-forming fluids using hydrothermal quartz from the 17.4 Ma Zhibula skarn, Tibet. Ion probe analysis reveals sharp and dramatic changes in quartz delta O-18 values between 5 parts per thousand and -9.3 parts per thousand, with fluid delta O-18 values varying between 2.8 parts per thousand and -18.2 parts per thousand, which are best explained by transient meteoric water incursion into a hydrothermal system dominated by magmatic fluids. Two pulses of magmatic fluids and a meteoric water incursion event are inferred, which operated at the millennium scale (760-1510 yr) as constrained by the aluminum diffusion chronometer. Our results indicate that magmatic reservoirs are likely water unsaturated for most of their lifetime (>10(5)-10(6) yr), with transient and episodic fluid exsolutions (similar to 10(3) yr) being driven by magma replenishment or crystallization-induced water saturation. With focused and efficient metal deposition, multiple pulses of metalliferous fluids favor the formation of giant deposits with high grade. Meteoric water delta O-18 values (-25.4 +/- 2.3 parts per thousand) derived from Zhibula quartz further suggest a paleo-elevation of 5.9 +/- 0.3 km; this transient early Miocene surface uplift plausibly was due to break-off of the oceanic slab attached to the Indian Plate. Our research highlights that ubiquitous hydrothermal quartz in orogenic belts can probe the dynamics of magmatic-hydrothermal systems and also quantify paleo-elevations, which has significant tectonic implications.
The novel working principle enables spiking cameras to capture high-speed moving objects. However, the applications of spiking cameras can be affected by many factors, such as brightness intensity, detectable distance, and the maximum speed of moving targets. Improper settings such as weak ambient brightness and too short object-camera distance, will lead to failure in the application of such cameras. To address the issue, this paper proposes a modeling algorithm that studies the detection capability of spiking cameras. The algorithm deduces the maximum detectable speed of spiking cameras corresponding to different scenario settings (e.g., brightness intensity, camera lens, and object-camera distance) based on the basic technical parameters of cameras (e.g., pixel size, spatial and temporal resolution). Thereby, the proper camera settings for various applications can be determined. Extensive experiments verify the effectiveness of the modeling algorithm. To our best knowledge, it is the first work to investigate the detection capability of spiking cameras.
Archaea are important participants in biogeochemical cycles of metal(loid)-polluted ecosystems, whereas archaeal structure and function in response to metal(loid) contamination remain poorly understood. Here, the effects of multiple metal(loid) pollution on the structure and function of archaeal communities were investigated in three zones within an abandoned sewage reservoir. We found that the high-contamination zone (Zone I) had higher archaeal diversity but a lower habitat niche breadth, relative to the mid-contamination zone (Zone II) and low-contamination zone (Zone III). Particularly, metal-resistant species represented by potential methanogens were markedly enriched in Zone I (cumulative relative abundance: 32.24%) compared to Zone II (1.93%) and Zone III (0.10%), and closer inter-taxon connections and higher network complexity (based on node number, edge number, and degree) were also observed compared to other zones. Meanwhile, the higher abundances of potential metal-resistant and methanogenic functions in Zone I (0.24% and 9.24%, respectively) than in Zone II (0.08% and 7.52%) and Zone III (0.01% and 1.03%) suggested archaeal functional adaptation to complex metal (loid) contamination. More importantly, six bioavailable metal(loid)s (titanium, tin, nickel, chromium, cobalt, and zinc) were the main contributors to archaeal community variations, and metal(loid) pollution reinforced the role of deterministic processes, particularly homogeneous selection, in the archaeal community assembly.