@article {JI2019373,
	title = {Sequestration of pertechnetate using carboxymethyl cellulose stabilized FeS nanoparticles: Effectiveness and mechanisms},
	journal = {Colloids and Surfaces A: Physicochemical and Engineering Aspects},
	volume = {561},
	year = {2019},
	pages = {373 - 380},
	abstract = {Technetium (99Tc) typically exists as pertechnetate (TcO4-) and hydrated oxide (TcO2{\textperiodcentered}nH2O) in soil and groundwater. While the former, Tc(VII), is very soluble and mobile in the environment, the latter is considered sparingly soluble and immobile. Consequently, immobilization of Tc(VII) can be achieved through conversion of Tc(VII) into Tc(IV). In this study, carboxymethyl cellulose (CMC) stabilized FeS nanoparticles (CMC-FeS) were prepared and tested for reductive immobilization of Tc(VII). Effects of nanoparticle dosage and water chemistry, including pH, humic acid and Ca2+ ions, were examined. At a dosage of 100 mg/L of CMC-FeS as Fe, CMC-FeS rapidly removed \&gt;96\% of 1.2 μM of Tc(VII) within 1 h, with a retarded first-order rate constant (ka) of 150.32 h-1. Higher pH in the range of 5.0{\textendash}9.0 favored the reaction, with an optimal pH range of 8.0{\textendash}9.0. While Ca2+ (up to 2 mM) only modestly affected the Tc(VII) removal, high concentrations of humic acid (up to 10 mg/L as TOC) showed increased inhibition on the Tc(VII) removal rate. FTIR and XPS analyses indicated that CMC-FeS immobilized TcO4- through reductive conversion of TcO4- into TcO2(s) and formation of Tc2S7 precipitate. The immobilized Tc remained insoluble when aged for 100 days under anoxic conditions, whereas up to 22.9\% of the immobilized Tc was remobilized when it was exposed to air for 100 days.},
	keywords = {Groundwater remediation, Radionuclide, Reductive immobilization, Soil remediation, Stabilized nanoparticles, Technetium},
	issn = {0927-7757},
	doi = {https://doi.org/10.1016/j.colsurfa.2018.10.048},
	url = {http://www.sciencedirect.com/science/article/pii/S0927775718307520},
	author = {Ji, Haodong and Yangmo Zhu and Liu, Wen and Michael J. Bozack and Qian, Tianwei and Zhao, Dongye}
}
